"Hot-wire Amperometric Monitoring Of Flowing Streams"
Talanta
2000 Volume 50, Issue 6 Pages 1205-1210
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Joseph Wang, Markus Jasinski, Gerd-Uwe Flechsig, Peter Grundler and Baomin Tian
Abstract:
This paper describes the design of a hot-wire electrochemical flow detector, and the advantages accrued from the effects of locally increased temperature, mainly thermally induced convection, upon the amperometric monitoring of flowing streams. A new hydrodynamic modulation voltammetric approach is presented, in which the solution flow rate remains constant while the temperature of the working electrode is modulated. Factors influencing the response, including the flow rate, temperature pulse, or applied potential, have been investigated. The hot-wire operation results also in a significant enhancement of the flow injection amperometric response. The minimal flow rate dependence observed with the heated electrode should benefit the on-line monitoring of streams with fluctuated natural convection, as well as various in-situ remote sensing applications.
Ferricyanide
Apparatus
Optimization
