"Evaluation Of A Split-type Flow Cell For A Polarized Spectrophotometric Detector"
Analyst 1995 Volume 120, Issue 4 Pages 1137-1139

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"Flow Injection Analysis With High-sensitivity Optical Rotation Detection"
Anal. Chem. 1994 Volume 66, Issue 19 Pages 3093-3101

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"Optimization Of A Polarized Photometric Detector Equipped With A Split-type Flow Cell And Its Analytical Application To Oligo-saccharides"
J. Pharm. Biomed. Anal. 1997 Volume 15, Issue 9-10 Pages 1383-1387

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		'abstract' => 'A novel, non-modulated polarimeter called a polarized photometric detector (PPD) was previously described by the authors. The PPD enables the measurement of the optical rotation of chiral compounds as a change in absorbance by placing two linear polarizers on either side of a flow cell of a conventional photometric detector. The present study describes the optimization of the conditions of PPD for highly sensitive detection of saccharides. To maximize the light intensity, the light balancing filter and slit were removed from the detector (Shimadzu model SPD-10AV). These modifications resulted in an approximately 15-fold increase in the incident light intensity when the maximum current was applied to the lamp. When this intense light was transmitted through the polarizers, the signal intensity followed the theoretical equation for phase angles up to around 1 rad. If the energy of the transmitted light was less than 700 mV, however, the baseline noise was too great to determine the chiral analyte accurately. Setting the phase angle between two polarizers at 50&deg;C and the detection wavelength at 400 nm provided the most suitable conditions. This detector was applicable for the determinations of oligosaccharides in foodstuffs separated by HPLC using gradient elution.',
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			'authors' => 'Yamamoto, A.;Matsunaga, A.;Mizukami, E.;Hayakawa, K.;Miyazaki, M.;Nishimura, M.;Kitaoka, M.;Fujita, T.',
			'authorsweb' => 'Atsushi Yamamoto, Akinobu Matsunaga, Eiichi Mizukami, Kazuichi Hayakawa, Motoichi Miyazaki, Masayuki Nishimura, Mitsuo Kitaoka and Tomio Fujita',
			'title' => 'Evaluation of a split-type flow cell for a polarized spectrophotometric detector',
			'journal' => 'Analyst',
			'journal_id' => '0864',
			'fadid' => 'ANAL1995V0120P01137',
			'year' => '1995',
			'volume' => '120',
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			'endpage' => '1139',
			'type' => 'Journal Article',
			'analytes' => '',
			'matrices' => '',
			'techniques' => ';0038;0388;0493;',
			'keywords' => ';0110;0167;0043;',
			'abstract' => 'A split-type flow cell for a polarized spectrophotometric detector (PPD), in which the column effluent is simultaneously passed through both the sample and reference sides, is described. The improvement in detection sensitivity in PPD with the use of this cell is discussed. Its utility as a universal polarimetric detector for HPLC for the detection of colored amino acid-copper(II) complexes is shown. A new possibility for this cell in the gradient elution separation of glucose syrup is demonstrated.',
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			'citation' => ''Evaluation of a split-type flow cell for a polarized spectrophotometric detector', Analyst, 1995 120(4) 1137-1139',
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			'authors' => 'Goss, C.A.;Wilson, D.C.;Weiser, W.E.',
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			'journal' => 'Anal. Chem.',
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			'fadid' => 'ANCH1994V0066P03093',
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			'abstract' => 'The construction and characterization of a flow injection analysis system with high-sensitivity, laser-based (488 nm), optical rotation detection (FIA-OR) is described. Baseline noise is reduced to - 10 &micro;deg by addition of a pressure pulsation damper between the pump and the autosampler. Sensitivity is increased 100-fold compared to a high-quality conventional polarimeter, and detection of a 43 ng sample of sucrose (25-pdeg rotation) is demonstrated. The instrument response is linear over a 500-fold range of concentration to 21 pg of sucrose injected, with the upper limit set by laser beam distortion caused by sample refractive index effects. Specific rotation values at 488 nm for 11 organic molecules are measured by FIA-OR with good precision and agree with values obtained by a conventional polarimeter. FIA-OR analysis of enantiomeric purity of (1S2R)-(+)-ephedrie is found to be more discriminating than conventional polarimetry for the analysis of solutions with high enantiomeric excess.',
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			'citation' => ''Flow injection analysis with high-sensitivity optical rotation detection', Anal. Chem., 1994 66(19) 3093-3101',
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			'title' => 'Theoretical consideration on polarized photometric detection',
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			'authors' => 'Goodall, D.M.',
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			'title' => 'Chiral analysis based on polarimetric detection',
			'journal' => 'Trends Anal. Chem.',
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			'abstract' => 'The use of laser polarimetry for chiral detection in HPLC and flow injection analysis is reviewed. (29 references).',
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include - APP/View/Elements/citation.ctp, line 40
View::_evaluate() - CORE/Cake/View/View.php, line 971
View::_render() - CORE/Cake/View/View.php, line 933
View::_renderElement() - CORE/Cake/View/View.php, line 1224
View::element() - CORE/Cake/View/View.php, line 418
include - APP/View/Techniques/view.ctp, line 52
View::_evaluate() - CORE/Cake/View/View.php, line 971
View::_render() - CORE/Cake/View/View.php, line 933
View::render() - CORE/Cake/View/View.php, line 473
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Dispatcher::_invoke() - CORE/Cake/Routing/Dispatcher.php, line 200
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"Theoretical Consideration On Polarized Photometric Detection"
Biomed. Chromatogr. 1994 Volume 8, Issue 3 Pages 130-133

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"Chiral Analysis Based On Polarimetric Detection"
Trends Anal. Chem. 1993 Volume 12, Issue 4 Pages 177-184

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			'type' => 'Application',
			'keyword' => 'Review',
			'newKeyword' => '',
			'synonyms' => '',
			'fao' => '',
			'total' => '897',
			'first' => 'R',
			'keytotal' => 'Review**897',
			'CitationsKeyword' => array(
				[maximum depth reached]
			)
		)
	)
)
$i = (int) 4
$path = ''
$a = ''
$url = 'http://dx.doi.org/10.1016/0165-9936(93)87020-X'
$aus = 'David M. Goodall'
include - APP/View/Elements/citation.ctp, line 40
View::_evaluate() - CORE/Cake/View/View.php, line 971
View::_render() - CORE/Cake/View/View.php, line 933
View::_renderElement() - CORE/Cake/View/View.php, line 1224
View::element() - CORE/Cake/View/View.php, line 418
include - APP/View/Techniques/view.ctp, line 52
View::_evaluate() - CORE/Cake/View/View.php, line 971
View::_render() - CORE/Cake/View/View.php, line 933
View::render() - CORE/Cake/View/View.php, line 473
Controller::render() - CORE/Cake/Controller/Controller.php, line 968
Dispatcher::_invoke() - CORE/Cake/Routing/Dispatcher.php, line 200
Dispatcher::dispatch() - CORE/Cake/Routing/Dispatcher.php, line 167
[main] - APP/webroot/index.php, line 109