Contact Info
Stuart Chalk, Ph.D.
Department of Chemistry
University of North Florida
Phone: 1-904-620-1938
Fax: 1-904-620-3535
Email: schalk@unf.edu
Website: @unf
Electrode
Citations 7
"Rapid Determination Of Sulfide In Waste Waters By Continuous-flow Analysis And Gas Diffusion And A Potentiometric Detector"
Anal. Chim. Acta
1984 Volume 163, Issue 1 Pages 293-297
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Brunt', 'title' => 'Rapid determination of sulfide in waste waters by continuous-flow analysis and gas diffusion and a potentiometric detector', 'journal' => 'Anal. Chim. Acta', 'journal_id' => '0584', 'fadid' => 'ANCA1984V0163P00293', 'year' => '1984', 'volume' => '163', 'issue' => '1', 'startpage' => '293', 'endpage' => '297', 'type' => 'Journal Article', 'analytes' => ';2237;', 'matrices' => ';1061;', 'techniques' => ';0330;0400;', 'keywords' => ';0173;0462;', 'abstract' => 'The system is based on a flow-through gaseous diffusion unit and potentiometric determination with a S2--selective electrode. In the range 0.5 to 600 ppm of S2-, the mean response is 30.2 mV per decade. The sampling rate is ~15 h-1, and the efficiency of transfer across the PTFE membrane is 48%. At S2- concentration. <50 ppm, the results obtained agreed well with those by a distillation method. 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Brunt', 'title' => 'Rapid determination of sulfide in waste waters by continuous-flow analysis and gas diffusion and a potentiometric detector', 'journal' => 'Anal. Chim. Acta', 'journal_id' => '0584', 'fadid' => 'ANCA1984V0163P00293', 'year' => '1984', 'volume' => '163', 'issue' => '1', 'startpage' => '293', 'endpage' => '297', 'type' => 'Journal Article', 'analytes' => ';2237;', 'matrices' => ';1061;', 'techniques' => ';0330;0400;', 'keywords' => ';0173;0462;', 'abstract' => 'The system is based on a flow-through gaseous diffusion unit and potentiometric determination with a S2--selective electrode. In the range 0.5 to 600 ppm of S2-, the mean response is 30.2 mV per decade. The sampling rate is ~15 h-1, and the efficiency of transfer across the PTFE membrane is 48%. At S2- concentration. <50 ppm, the results obtained agreed well with those by a distillation method. 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Acta, 1984 163(1) 293-297', 'firstchar' => 'R', 'twochars' => 'Ra', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array( [maximum depth reached] ), 'Keyword' => array( [maximum depth reached] ) ), (int) 1 => array( 'id' => '007384', 'authors' => 'Glaister, M.G.;Moody, G.J.;Thomas, J.D.R.', 'authorsweb' => 'M. G. Glaister, G. J. Moody and J. D. R. Thomas', 'title' => 'Studies on flow injection analysis with sulfide ion-selective electrodes', 'journal' => 'Analyst', 'journal_id' => '0864', 'fadid' => 'ANAL1985V0110P00113', 'year' => '1985', 'volume' => '110', 'issue' => '2', 'startpage' => '113', 'endpage' => '119', 'type' => 'Journal Article', 'analytes' => ';2237;', 'matrices' => ';1061;', 'techniques' => ';0330;0400;', 'keywords' => ';0217;0258;', 'abstract' => 'The Orion Model 94-16A, EDT Research EES and EDT Research EES flow-through electrodes were tested and shown to yield near-Nernstian slopes of response between 1 µM and 0.01 M and 0.01 M S2-. Interference by H2O2 can be controlled by adding antioxidant buffer (4% of ascorbic acid in 2 M NaOH). Reconditioning of affected electrodes may be achieved by soaking in 0.1 M Na2S for 48 h and then polishing the membrane surface. For flow injection analysis a carrier stream (2.23 mL min-1) containing 5 µM-Na2S in a medium of 2% of ascorbic acid in 2 M NaOH was suitable for analysis of sewage effluent samples in a 12-cm x 1.3-mm flow tube. For determination of S2- in sewage, flow injection analysis was superior to direct potentiometry. Both the Orion Model 94-16 and EDT Research EES 'flow-through' electrodes yielded values for S2- similar to those obtained colorimetrically. Sulfide contents ranged from 0.1 to 17.8 ppm, the lower level relating to samples pre-treated with H2O2 as a recognized method of controlling adverse sulfidic species in effluent.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '5', 'urlcheck' => '2014-10-12 00:00:39', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => '01339', 'pauthor' => '!Thomas, J.D.R.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1039/an9851000113', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Studies on flow injection analysis with sulfide ion-selective electrodes', Analyst, 1985 110(2) 113-119', 'firstchar' => 'S', 'twochars' => 'St', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array( [maximum depth reached] ), 'Keyword' => array( [maximum depth reached] ) ), (int) 2 => array( 'id' => '007491', 'authors' => 'Van Staden, J.F.', 'authorsweb' => 'Jacobus F. van Staden', 'title' => 'Determination of sulfide using flow injection analysis with a coated tubular solid-state silver-sulfide ion-selective electrode', 'journal' => 'Analyst', 'journal_id' => '0864', 'fadid' => 'ANAL1988V0113P00885', 'year' => '1988', 'volume' => '113', 'issue' => '6', 'startpage' => '885', 'endpage' => '889', 'type' => 'Journal Article', 'analytes' => ';2237;', 'matrices' => ';1061;', 'techniques' => ';0224;0330;0400;', 'keywords' => ';0217;', 'abstract' => 'The electrode described previously (cf., e.g., Anal. Abstr, 1987, 49, 7J12) was activated by deposition of Ag2S as a fine membrane on the inner wall of the tubular cylinder, conditioned for >24 h in 0.1 M Na2S, and incorporated into a flow injection system containing an Orion 90-02 double-junction reference electrode. The performance of the electrode was evaluated by using 1 M KNO3 or sulfide antioxidant buffer solution as carrier stream, and a working range of up to 1 g L-1 was established for determination of S2- (injection volume 30 µL). Results compared favourably with those obtained with a commercial cascade mode electrode, and sensitivity was improved (detection limit 0.4 mg l-1). Mercury, Br-, I-, CN- and S2O32- interfered. The electrode was applied in the determination of S2- in effluents, and the coefficient of variation (n = 15) ranged from 0.9 to 1.8%. Recoveries of S2- added to water ranged from 96 to 104%.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '6', 'urlcheck' => '2014-10-12 00:03:32', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => '00328', 'pauthor' => '!Van Staden, J.F.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1039/an9881300885', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Determination of sulfide using flow injection analysis with a coated tubular solid-state silver-sulfide ion-selective electrode', Analyst, 1988 113(6) 885-889', 'firstchar' => 'D', 'twochars' => 'De', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array( [maximum depth reached] ), 'Keyword' => array( [maximum depth reached] ) ), (int) 3 => array( 'id' => '009912', 'authors' => 'Davey, D.E.;Mulcahy, D.E.;O'Connell, G.R.', 'authorsweb' => 'David E. Davey, Dennis E. Mulcahy, Gregory R. O'Connell*', 'title' => 'Effect of membrane composition on the flow injection response of an ion-selective electrode: a comparative study based an selectivity coefficients calculated using a data linearization technique', 'journal' => 'Electroanalysis', 'journal_id' => '1003', 'fadid' => 'ELAN1996V0008P00274', 'year' => '1996', 'volume' => '8', 'issue' => '3', 'startpage' => '274', 'endpage' => '279', 'type' => 'Journal Article', 'analytes' => ';1275;', 'matrices' => '', 'techniques' => ';0303;0284;0330;0400;', 'keywords' => ';0217;', 'abstract' => 'Portions of 100 µL of iodide solutions containing 100 mM bromide, thiocyanate and thiosulfate as interferents were injected into carrier and reagent streams (total flow 6.6 ml/min) of 1 µM-KI and 100 mM KNO3, and iodide detected using a variety of purpose made AgI/Ag2S (details given) and commercially available iodide, sulfide and cadmium ISE. Calibration graphs of the respective ISE responses are presented. Most sensors showed good analytical performance, excepting that prepared from a 3:1 AgI/Ag2S membrane.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '8', 'urlcheck' => '2014-10-11 14:10:51', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => '01201', 'pauthor' => '!O'Connell, G.R.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1002/elan.1140080313', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Effect of membrane composition on the flow injection response of an ion-selective electrode: a comparative study based an selectivity coefficients calculated using a data linearization technique', Electroanalysis, 1996 8(3) 274-279', 'firstchar' => 'E', 'twochars' => 'Ef', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array([maximum depth reached]), 'Keyword' => array( [maximum depth reached] ) ), (int) 4 => array( 'id' => '010806', 'authors' => 'Duffield, E.J.;Moody, G.J.;Thomas, J.D.R.', 'authorsweb' => 'E. Jane Duffield, G. J. Moody, J. D. R. Thomas', 'title' => 'Development of ion-selective electrodes and flow injection analysis for sulfides and thiols', 'journal' => 'Anal. Proc.', 'journal_id' => '0866', 'fadid' => 'ANPR1980V0017P00533', 'year' => '1980', 'volume' => '17', 'issue' => '12', 'startpage' => '533', 'endpage' => '535', 'type' => 'Journal Article', 'analytes' => ';2237;2328;', 'matrices' => 'NA', 'techniques' => ';0330;0127;0213;', 'keywords' => 'NA', 'abstract' => 'The flow injection analysis system was used to control difficulties arising in the response of Ag sulfide membrane ion-selective electrodes to sulfides and thiols due to oxidation and volatility. Reproducible flow injection emf. response peaks were obtained for S2- standards at 10^-4-10-1M.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '2006-08-28 08:56:29', 'hits' => '10', 'urlcheck' => '2014-10-11 21:09:16', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => null, 'pauthor' => 'NA', 'address' => 'NA', 'email' => 'NA', 'notes' => null, 'url' => '10.1039/ap9801700533', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Development of ion-selective electrodes and flow injection analysis for sulfides and thiols', Anal. Proc., 1980 17(12) 533-535', 'firstchar' => 'D', 'twochars' => 'De', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array([maximum depth reached]), 'Keyword' => array([maximum depth reached]) ), (int) 5 => array( 'id' => '012785', 'authors' => 'Wang, L.J.;Zhang, S.;Zhu, Y.M.;Wang, Q.S.', 'authorsweb' => 'Wang, Lijun; Zhang, Shen; Zhu, Yangming; Wang, Qinsheng', 'title' => 'Rapid determination of sulfide in water by flow injection analysis', 'journal' => 'Huanjing Huaxue', 'journal_id' => '0887', 'fadid' => 'HJHX1983V0002P00064', 'year' => '1983', 'volume' => '2', 'issue' => '3', 'startpage' => '64', 'endpage' => '68', 'type' => 'Journal Article', 'analytes' => ';2237;', 'matrices' => ';1079;', 'techniques' => ';0330;', 'keywords' => ';0217;', 'abstract' => 'Sulfide in water was determined by flow injection analysis (FIA) using methylene blue spectrophotometry with a linear calibration for concentrations in the range 3.5-200 mM. The relative standard deviation was 1.05% for 20 determinations of a 56.0 mM S2- sample. Cr(VI) at <0.5 mM shows no interference in the analysis The method can be used to analyze 60-80 samples/h.', 'language' => 'Chinese', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'No', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '0', 'urlcheck' => '2014-10-13 09:59:23', 'urlcheckcode' => 'HTTP/1.1 200 OK', 'pauthor_id' => null, 'pauthor' => 'NA', 'address' => 'Institute of Geography, Academia Sinica, Beijing China', 'email' => 'NA', 'notes' => null, 'url' => 'hjhx.rcees.ac.cn/hjhx/homeAction!downloadArticleFile.action?attachType=PDF&id=3744', 'urltype' => 'pdfurl', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Rapid determination of sulfide in water by flow injection analysis', Huanjing Huaxue, 1983 2(3) 64-68', 'firstchar' => 'R', 'twochars' => 'Ra', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array( [maximum depth reached] ), 'Keyword' => array( [maximum depth reached] ) ), (int) 6 => array( 'id' => '012877', 'authors' => 'Thomas, J.D.R.', 'authorsweb' => 'NA', 'title' => 'Electrochemical analysis of sulfur compounds of environmental interest', 'journal' => 'Int. J. Environ. Anal. Chem.', 'journal_id' => '0734', 'fadid' => 'IEAC1985V0020P00167', 'year' => '1985', 'volume' => '20', 'issue' => '3-4', 'startpage' => '167', 'endpage' => '177', 'type' => 'Journal Article', 'analytes' => ';2237;', 'matrices' => ';0404;1061;0630;', 'techniques' => ';0330;', 'keywords' => ';0217;0389;', 'abstract' => 'A review is presented, largely of work carried out at UWIST, with emphasis on the use of S2--selective electrodes for monitoring industrial liquors (e.g., black liquor) and effluents and sewage effluents and for monitoring the growth of S2--producing bacteria, of importance in the context of industrial spoilage, and also on flow injection analysis with use of ion-selective electrodes and on means of overcoming interference by H2O2. (30 references).', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'No', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '5', 'urlcheck' => '2014-10-12 00:22:14', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => '01339', 'pauthor' => '!Thomas, J.D.R.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1080/03067318508077055', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Electrochemical analysis of sulfur compounds of environmental interest', Int. J. Environ. Anal. Chem., 1985 20(3-4) 167-177', 'firstchar' => 'E', 'twochars' => 'El', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array( [maximum depth reached] ), 'Keyword' => array( [maximum depth reached] ) ) ) ) $c = array( 'id' => '004637', 'authors' => 'Brunt, K.', 'authorsweb' => 'K. 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"Studies On Flow Injection Analysis With Sulfide Ion-selective Electrodes"
Analyst
1985 Volume 110, Issue 2 Pages 113-119
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D. R. Thomas', 'title' => 'Studies on flow injection analysis with sulfide ion-selective electrodes', 'journal' => 'Analyst', 'journal_id' => '0864', 'fadid' => 'ANAL1985V0110P00113', 'year' => '1985', 'volume' => '110', 'issue' => '2', 'startpage' => '113', 'endpage' => '119', 'type' => 'Journal Article', 'analytes' => ';2237;', 'matrices' => ';1061;', 'techniques' => ';0330;0400;', 'keywords' => ';0217;0258;', 'abstract' => 'The Orion Model 94-16A, EDT Research EES and EDT Research EES flow-through electrodes were tested and shown to yield near-Nernstian slopes of response between 1 µM and 0.01 M and 0.01 M S2-. Interference by H2O2 can be controlled by adding antioxidant buffer (4% of ascorbic acid in 2 M NaOH). Reconditioning of affected electrodes may be achieved by soaking in 0.1 M Na2S for 48 h and then polishing the membrane surface. For flow injection analysis a carrier stream (2.23 mL min-1) containing 5 µM-Na2S in a medium of 2% of ascorbic acid in 2 M NaOH was suitable for analysis of sewage effluent samples in a 12-cm x 1.3-mm flow tube. For determination of S2- in sewage, flow injection analysis was superior to direct potentiometry. Both the Orion Model 94-16 and EDT Research EES 'flow-through' electrodes yielded values for S2- similar to those obtained colorimetrically. Sulfide contents ranged from 0.1 to 17.8 ppm, the lower level relating to samples pre-treated with H2O2 as a recognized method of controlling adverse sulfidic species in effluent.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '5', 'urlcheck' => '2014-10-12 00:00:39', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => '01339', 'pauthor' => '!Thomas, J.D.R.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1039/an9851000113', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Studies on flow injection analysis with sulfide ion-selective electrodes', Analyst, 1985 110(2) 113-119', 'firstchar' => 'S', 'twochars' => 'St', 'CitationsTechnique' => array( 'id' => '004424', 'citation_id' => '007384', 'technique_id' => '0330' ), 'Analyte' => array( (int) 0 => array( [maximum depth reached] ) ), 'Matrix' => array( (int) 0 => array( [maximum depth reached] ) ), 'Keyword' => array( (int) 0 => array( [maximum depth reached] ), (int) 1 => array( [maximum depth reached] ) ) ), 'i' => (int) 1 ) $data = array( 'Technique' => array( 'id' => '0330', 'label' => 'Electrode', 'level1' => 'Electrode', 'level2' => 'ion selective', 'level3' => 'sulfide', 'level4' => '', 'level5' => '', 'synonyms' => 'Ion selective electrode,ISE', 'champ' => '', 'total' => '7', 'updated' => '0000-00-00 00:00:00', 'name' => 'Electrode, ion selective, sulfide', 'nametotal' => 'Electrode, ion selective, sulfide**7', 'first' => 'E' ), 'Citation' => array( (int) 0 => array( 'id' => '004637', 'authors' => 'Brunt, K.', 'authorsweb' => 'K. Brunt', 'title' => 'Rapid determination of sulfide in waste waters by continuous-flow analysis and gas diffusion and a potentiometric detector', 'journal' => 'Anal. Chim. Acta', 'journal_id' => '0584', 'fadid' => 'ANCA1984V0163P00293', 'year' => '1984', 'volume' => '163', 'issue' => '1', 'startpage' => '293', 'endpage' => '297', 'type' => 'Journal Article', 'analytes' => ';2237;', 'matrices' => ';1061;', 'techniques' => ';0330;0400;', 'keywords' => ';0173;0462;', 'abstract' => 'The system is based on a flow-through gaseous diffusion unit and potentiometric determination with a S2--selective electrode. In the range 0.5 to 600 ppm of S2-, the mean response is 30.2 mV per decade. The sampling rate is ~15 h-1, and the efficiency of transfer across the PTFE membrane is 48%. At S2- concentration. <50 ppm, the results obtained agreed well with those by a distillation method. Apparent losses at higher concentration. in the proposed method are ascribed to incorrect sample storage, problems of which are discussed.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '4', 'urlcheck' => '2014-10-11 15:46:39', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => null, 'pauthor' => '!Brunt, K.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1016/S0003-2670(00)81521-4', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Rapid determination of sulfide in waste waters by continuous-flow analysis and gas diffusion and a potentiometric detector', Anal. Chim. Acta, 1984 163(1) 293-297', 'firstchar' => 'R', 'twochars' => 'Ra', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array( [maximum depth reached] ), 'Keyword' => array( [maximum depth reached] ) ), (int) 1 => array( 'id' => '007384', 'authors' => 'Glaister, M.G.;Moody, G.J.;Thomas, J.D.R.', 'authorsweb' => 'M. G. Glaister, G. J. Moody and J. D. R. Thomas', 'title' => 'Studies on flow injection analysis with sulfide ion-selective electrodes', 'journal' => 'Analyst', 'journal_id' => '0864', 'fadid' => 'ANAL1985V0110P00113', 'year' => '1985', 'volume' => '110', 'issue' => '2', 'startpage' => '113', 'endpage' => '119', 'type' => 'Journal Article', 'analytes' => ';2237;', 'matrices' => ';1061;', 'techniques' => ';0330;0400;', 'keywords' => ';0217;0258;', 'abstract' => 'The Orion Model 94-16A, EDT Research EES and EDT Research EES flow-through electrodes were tested and shown to yield near-Nernstian slopes of response between 1 µM and 0.01 M and 0.01 M S2-. Interference by H2O2 can be controlled by adding antioxidant buffer (4% of ascorbic acid in 2 M NaOH). Reconditioning of affected electrodes may be achieved by soaking in 0.1 M Na2S for 48 h and then polishing the membrane surface. For flow injection analysis a carrier stream (2.23 mL min-1) containing 5 µM-Na2S in a medium of 2% of ascorbic acid in 2 M NaOH was suitable for analysis of sewage effluent samples in a 12-cm x 1.3-mm flow tube. For determination of S2- in sewage, flow injection analysis was superior to direct potentiometry. Both the Orion Model 94-16 and EDT Research EES 'flow-through' electrodes yielded values for S2- similar to those obtained colorimetrically. Sulfide contents ranged from 0.1 to 17.8 ppm, the lower level relating to samples pre-treated with H2O2 as a recognized method of controlling adverse sulfidic species in effluent.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '5', 'urlcheck' => '2014-10-12 00:00:39', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => '01339', 'pauthor' => '!Thomas, J.D.R.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1039/an9851000113', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Studies on flow injection analysis with sulfide ion-selective electrodes', Analyst, 1985 110(2) 113-119', 'firstchar' => 'S', 'twochars' => 'St', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array( [maximum depth reached] ), 'Keyword' => array( [maximum depth reached] ) ), (int) 2 => array( 'id' => '007491', 'authors' => 'Van Staden, J.F.', 'authorsweb' => 'Jacobus F. van Staden', 'title' => 'Determination of sulfide using flow injection analysis with a coated tubular solid-state silver-sulfide ion-selective electrode', 'journal' => 'Analyst', 'journal_id' => '0864', 'fadid' => 'ANAL1988V0113P00885', 'year' => '1988', 'volume' => '113', 'issue' => '6', 'startpage' => '885', 'endpage' => '889', 'type' => 'Journal Article', 'analytes' => ';2237;', 'matrices' => ';1061;', 'techniques' => ';0224;0330;0400;', 'keywords' => ';0217;', 'abstract' => 'The electrode described previously (cf., e.g., Anal. Abstr, 1987, 49, 7J12) was activated by deposition of Ag2S as a fine membrane on the inner wall of the tubular cylinder, conditioned for >24 h in 0.1 M Na2S, and incorporated into a flow injection system containing an Orion 90-02 double-junction reference electrode. The performance of the electrode was evaluated by using 1 M KNO3 or sulfide antioxidant buffer solution as carrier stream, and a working range of up to 1 g L-1 was established for determination of S2- (injection volume 30 µL). Results compared favourably with those obtained with a commercial cascade mode electrode, and sensitivity was improved (detection limit 0.4 mg l-1). Mercury, Br-, I-, CN- and S2O32- interfered. The electrode was applied in the determination of S2- in effluents, and the coefficient of variation (n = 15) ranged from 0.9 to 1.8%. Recoveries of S2- added to water ranged from 96 to 104%.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '6', 'urlcheck' => '2014-10-12 00:03:32', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => '00328', 'pauthor' => '!Van Staden, J.F.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1039/an9881300885', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Determination of sulfide using flow injection analysis with a coated tubular solid-state silver-sulfide ion-selective electrode', Analyst, 1988 113(6) 885-889', 'firstchar' => 'D', 'twochars' => 'De', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array( [maximum depth reached] ), 'Keyword' => array( [maximum depth reached] ) ), (int) 3 => array( 'id' => '009912', 'authors' => 'Davey, D.E.;Mulcahy, D.E.;O'Connell, G.R.', 'authorsweb' => 'David E. Davey, Dennis E. Mulcahy, Gregory R. O'Connell*', 'title' => 'Effect of membrane composition on the flow injection response of an ion-selective electrode: a comparative study based an selectivity coefficients calculated using a data linearization technique', 'journal' => 'Electroanalysis', 'journal_id' => '1003', 'fadid' => 'ELAN1996V0008P00274', 'year' => '1996', 'volume' => '8', 'issue' => '3', 'startpage' => '274', 'endpage' => '279', 'type' => 'Journal Article', 'analytes' => ';1275;', 'matrices' => '', 'techniques' => ';0303;0284;0330;0400;', 'keywords' => ';0217;', 'abstract' => 'Portions of 100 µL of iodide solutions containing 100 mM bromide, thiocyanate and thiosulfate as interferents were injected into carrier and reagent streams (total flow 6.6 ml/min) of 1 µM-KI and 100 mM KNO3, and iodide detected using a variety of purpose made AgI/Ag2S (details given) and commercially available iodide, sulfide and cadmium ISE. Calibration graphs of the respective ISE responses are presented. Most sensors showed good analytical performance, excepting that prepared from a 3:1 AgI/Ag2S membrane.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '8', 'urlcheck' => '2014-10-11 14:10:51', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => '01201', 'pauthor' => '!O'Connell, G.R.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1002/elan.1140080313', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Effect of membrane composition on the flow injection response of an ion-selective electrode: a comparative study based an selectivity coefficients calculated using a data linearization technique', Electroanalysis, 1996 8(3) 274-279', 'firstchar' => 'E', 'twochars' => 'Ef', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array([maximum depth reached]), 'Keyword' => array( [maximum depth reached] ) ), (int) 4 => array( 'id' => '010806', 'authors' => 'Duffield, E.J.;Moody, G.J.;Thomas, J.D.R.', 'authorsweb' => 'E. Jane Duffield, G. J. Moody, J. D. R. Thomas', 'title' => 'Development of ion-selective electrodes and flow injection analysis for sulfides and thiols', 'journal' => 'Anal. Proc.', 'journal_id' => '0866', 'fadid' => 'ANPR1980V0017P00533', 'year' => '1980', 'volume' => '17', 'issue' => '12', 'startpage' => '533', 'endpage' => '535', 'type' => 'Journal Article', 'analytes' => ';2237;2328;', 'matrices' => 'NA', 'techniques' => ';0330;0127;0213;', 'keywords' => 'NA', 'abstract' => 'The flow injection analysis system was used to control difficulties arising in the response of Ag sulfide membrane ion-selective electrodes to sulfides and thiols due to oxidation and volatility. Reproducible flow injection emf. response peaks were obtained for S2- standards at 10^-4-10-1M.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '2006-08-28 08:56:29', 'hits' => '10', 'urlcheck' => '2014-10-11 21:09:16', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => null, 'pauthor' => 'NA', 'address' => 'NA', 'email' => 'NA', 'notes' => null, 'url' => '10.1039/ap9801700533', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Development of ion-selective electrodes and flow injection analysis for sulfides and thiols', Anal. Proc., 1980 17(12) 533-535', 'firstchar' => 'D', 'twochars' => 'De', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array([maximum depth reached]), 'Keyword' => array([maximum depth reached]) ), (int) 5 => array( 'id' => '012785', 'authors' => 'Wang, L.J.;Zhang, S.;Zhu, Y.M.;Wang, Q.S.', 'authorsweb' => 'Wang, Lijun; Zhang, Shen; Zhu, Yangming; Wang, Qinsheng', 'title' => 'Rapid determination of sulfide in water by flow injection analysis', 'journal' => 'Huanjing Huaxue', 'journal_id' => '0887', 'fadid' => 'HJHX1983V0002P00064', 'year' => '1983', 'volume' => '2', 'issue' => '3', 'startpage' => '64', 'endpage' => '68', 'type' => 'Journal Article', 'analytes' => ';2237;', 'matrices' => ';1079;', 'techniques' => ';0330;', 'keywords' => ';0217;', 'abstract' => 'Sulfide in water was determined by flow injection analysis (FIA) using methylene blue spectrophotometry with a linear calibration for concentrations in the range 3.5-200 mM. The relative standard deviation was 1.05% for 20 determinations of a 56.0 mM S2- sample. Cr(VI) at <0.5 mM shows no interference in the analysis The method can be used to analyze 60-80 samples/h.', 'language' => 'Chinese', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'No', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '0', 'urlcheck' => '2014-10-13 09:59:23', 'urlcheckcode' => 'HTTP/1.1 200 OK', 'pauthor_id' => null, 'pauthor' => 'NA', 'address' => 'Institute of Geography, Academia Sinica, Beijing China', 'email' => 'NA', 'notes' => null, 'url' => 'hjhx.rcees.ac.cn/hjhx/homeAction!downloadArticleFile.action?attachType=PDF&id=3744', 'urltype' => 'pdfurl', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Rapid determination of sulfide in water by flow injection analysis', Huanjing Huaxue, 1983 2(3) 64-68', 'firstchar' => 'R', 'twochars' => 'Ra', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array( [maximum depth reached] ), 'Keyword' => array( [maximum depth reached] ) ), (int) 6 => array( 'id' => '012877', 'authors' => 'Thomas, J.D.R.', 'authorsweb' => 'NA', 'title' => 'Electrochemical analysis of sulfur compounds of environmental interest', 'journal' => 'Int. J. Environ. Anal. Chem.', 'journal_id' => '0734', 'fadid' => 'IEAC1985V0020P00167', 'year' => '1985', 'volume' => '20', 'issue' => '3-4', 'startpage' => '167', 'endpage' => '177', 'type' => 'Journal Article', 'analytes' => ';2237;', 'matrices' => ';0404;1061;0630;', 'techniques' => ';0330;', 'keywords' => ';0217;0389;', 'abstract' => 'A review is presented, largely of work carried out at UWIST, with emphasis on the use of S2--selective electrodes for monitoring industrial liquors (e.g., black liquor) and effluents and sewage effluents and for monitoring the growth of S2--producing bacteria, of importance in the context of industrial spoilage, and also on flow injection analysis with use of ion-selective electrodes and on means of overcoming interference by H2O2. (30 references).', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'No', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '5', 'urlcheck' => '2014-10-12 00:22:14', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => '01339', 'pauthor' => '!Thomas, J.D.R.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1080/03067318508077055', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Electrochemical analysis of sulfur compounds of environmental interest', Int. J. Environ. Anal. Chem., 1985 20(3-4) 167-177', 'firstchar' => 'E', 'twochars' => 'El', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array( [maximum depth reached] ), 'Keyword' => array( [maximum depth reached] ) ) ) ) $c = array( 'id' => '007384', 'authors' => 'Glaister, M.G.;Moody, G.J.;Thomas, J.D.R.', 'authorsweb' => 'M. G. Glaister, G. J. Moody and J. D. R. 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"Determination Of Sulfide Using Flow Injection Analysis With A Coated Tubular Solid-state Silver-sulfide Ion-selective Electrode"
Analyst
1988 Volume 113, Issue 6 Pages 885-889
Notice (8): Undefined variable: uid [APP/View/Elements/citation.ctp, line 40]Jacobus F. van StadenCode Context?>
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Abstr, 1987, 49, 7J12) was activated by deposition of Ag2S as a fine membrane on the inner wall of the tubular cylinder, conditioned for >24 h in 0.1 M Na2S, and incorporated into a flow injection system containing an Orion 90-02 double-junction reference electrode. The performance of the electrode was evaluated by using 1 M KNO3 or sulfide antioxidant buffer solution as carrier stream, and a working range of up to 1 g L-1 was established for determination of S2- (injection volume 30 µL). Results compared favourably with those obtained with a commercial cascade mode electrode, and sensitivity was improved (detection limit 0.4 mg l-1). Mercury, Br-, I-, CN- and S2O32- interfered. The electrode was applied in the determination of S2- in effluents, and the coefficient of variation (n = 15) ranged from 0.9 to 1.8%. 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Apparent losses at higher concentration. in the proposed method are ascribed to incorrect sample storage, problems of which are discussed.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '4', 'urlcheck' => '2014-10-11 15:46:39', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => null, 'pauthor' => '!Brunt, K.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1016/S0003-2670(00)81521-4', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Rapid determination of sulfide in waste waters by continuous-flow analysis and gas diffusion and a potentiometric detector', Anal. Chim. Acta, 1984 163(1) 293-297', 'firstchar' => 'R', 'twochars' => 'Ra', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array( [maximum depth reached] ), 'Keyword' => array( [maximum depth reached] ) ), (int) 1 => array( 'id' => '007384', 'authors' => 'Glaister, M.G.;Moody, G.J.;Thomas, J.D.R.', 'authorsweb' => 'M. G. Glaister, G. J. Moody and J. D. R. Thomas', 'title' => 'Studies on flow injection analysis with sulfide ion-selective electrodes', 'journal' => 'Analyst', 'journal_id' => '0864', 'fadid' => 'ANAL1985V0110P00113', 'year' => '1985', 'volume' => '110', 'issue' => '2', 'startpage' => '113', 'endpage' => '119', 'type' => 'Journal Article', 'analytes' => ';2237;', 'matrices' => ';1061;', 'techniques' => ';0330;0400;', 'keywords' => ';0217;0258;', 'abstract' => 'The Orion Model 94-16A, EDT Research EES and EDT Research EES flow-through electrodes were tested and shown to yield near-Nernstian slopes of response between 1 µM and 0.01 M and 0.01 M S2-. Interference by H2O2 can be controlled by adding antioxidant buffer (4% of ascorbic acid in 2 M NaOH). Reconditioning of affected electrodes may be achieved by soaking in 0.1 M Na2S for 48 h and then polishing the membrane surface. For flow injection analysis a carrier stream (2.23 mL min-1) containing 5 µM-Na2S in a medium of 2% of ascorbic acid in 2 M NaOH was suitable for analysis of sewage effluent samples in a 12-cm x 1.3-mm flow tube. For determination of S2- in sewage, flow injection analysis was superior to direct potentiometry. Both the Orion Model 94-16 and EDT Research EES 'flow-through' electrodes yielded values for S2- similar to those obtained colorimetrically. Sulfide contents ranged from 0.1 to 17.8 ppm, the lower level relating to samples pre-treated with H2O2 as a recognized method of controlling adverse sulfidic species in effluent.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '5', 'urlcheck' => '2014-10-12 00:00:39', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => '01339', 'pauthor' => '!Thomas, J.D.R.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1039/an9851000113', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Studies on flow injection analysis with sulfide ion-selective electrodes', Analyst, 1985 110(2) 113-119', 'firstchar' => 'S', 'twochars' => 'St', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array( [maximum depth reached] ), 'Keyword' => array( [maximum depth reached] ) ), (int) 2 => array( 'id' => '007491', 'authors' => 'Van Staden, J.F.', 'authorsweb' => 'Jacobus F. van Staden', 'title' => 'Determination of sulfide using flow injection analysis with a coated tubular solid-state silver-sulfide ion-selective electrode', 'journal' => 'Analyst', 'journal_id' => '0864', 'fadid' => 'ANAL1988V0113P00885', 'year' => '1988', 'volume' => '113', 'issue' => '6', 'startpage' => '885', 'endpage' => '889', 'type' => 'Journal Article', 'analytes' => ';2237;', 'matrices' => ';1061;', 'techniques' => ';0224;0330;0400;', 'keywords' => ';0217;', 'abstract' => 'The electrode described previously (cf., e.g., Anal. Abstr, 1987, 49, 7J12) was activated by deposition of Ag2S as a fine membrane on the inner wall of the tubular cylinder, conditioned for >24 h in 0.1 M Na2S, and incorporated into a flow injection system containing an Orion 90-02 double-junction reference electrode. The performance of the electrode was evaluated by using 1 M KNO3 or sulfide antioxidant buffer solution as carrier stream, and a working range of up to 1 g L-1 was established for determination of S2- (injection volume 30 µL). Results compared favourably with those obtained with a commercial cascade mode electrode, and sensitivity was improved (detection limit 0.4 mg l-1). Mercury, Br-, I-, CN- and S2O32- interfered. The electrode was applied in the determination of S2- in effluents, and the coefficient of variation (n = 15) ranged from 0.9 to 1.8%. 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Davey, Dennis E. Mulcahy, Gregory R. O'Connell*', 'title' => 'Effect of membrane composition on the flow injection response of an ion-selective electrode: a comparative study based an selectivity coefficients calculated using a data linearization technique', 'journal' => 'Electroanalysis', 'journal_id' => '1003', 'fadid' => 'ELAN1996V0008P00274', 'year' => '1996', 'volume' => '8', 'issue' => '3', 'startpage' => '274', 'endpage' => '279', 'type' => 'Journal Article', 'analytes' => ';1275;', 'matrices' => '', 'techniques' => ';0303;0284;0330;0400;', 'keywords' => ';0217;', 'abstract' => 'Portions of 100 µL of iodide solutions containing 100 mM bromide, thiocyanate and thiosulfate as interferents were injected into carrier and reagent streams (total flow 6.6 ml/min) of 1 µM-KI and 100 mM KNO3, and iodide detected using a variety of purpose made AgI/Ag2S (details given) and commercially available iodide, sulfide and cadmium ISE. Calibration graphs of the respective ISE responses are presented. Most sensors showed good analytical performance, excepting that prepared from a 3:1 AgI/Ag2S membrane.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '8', 'urlcheck' => '2014-10-11 14:10:51', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => '01201', 'pauthor' => '!O'Connell, G.R.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1002/elan.1140080313', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Effect of membrane composition on the flow injection response of an ion-selective electrode: a comparative study based an selectivity coefficients calculated using a data linearization technique', Electroanalysis, 1996 8(3) 274-279', 'firstchar' => 'E', 'twochars' => 'Ef', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array([maximum depth reached]), 'Keyword' => array( [maximum depth reached] ) ), (int) 4 => array( 'id' => '010806', 'authors' => 'Duffield, E.J.;Moody, G.J.;Thomas, J.D.R.', 'authorsweb' => 'E. Jane Duffield, G. J. Moody, J. D. R. Thomas', 'title' => 'Development of ion-selective electrodes and flow injection analysis for sulfides and thiols', 'journal' => 'Anal. Proc.', 'journal_id' => '0866', 'fadid' => 'ANPR1980V0017P00533', 'year' => '1980', 'volume' => '17', 'issue' => '12', 'startpage' => '533', 'endpage' => '535', 'type' => 'Journal Article', 'analytes' => ';2237;2328;', 'matrices' => 'NA', 'techniques' => ';0330;0127;0213;', 'keywords' => 'NA', 'abstract' => 'The flow injection analysis system was used to control difficulties arising in the response of Ag sulfide membrane ion-selective electrodes to sulfides and thiols due to oxidation and volatility. Reproducible flow injection emf. response peaks were obtained for S2- standards at 10^-4-10-1M.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '2006-08-28 08:56:29', 'hits' => '10', 'urlcheck' => '2014-10-11 21:09:16', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => null, 'pauthor' => 'NA', 'address' => 'NA', 'email' => 'NA', 'notes' => null, 'url' => '10.1039/ap9801700533', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Development of ion-selective electrodes and flow injection analysis for sulfides and thiols', Anal. Proc., 1980 17(12) 533-535', 'firstchar' => 'D', 'twochars' => 'De', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array([maximum depth reached]), 'Keyword' => array([maximum depth reached]) ), (int) 5 => array( 'id' => '012785', 'authors' => 'Wang, L.J.;Zhang, S.;Zhu, Y.M.;Wang, Q.S.', 'authorsweb' => 'Wang, Lijun; Zhang, Shen; Zhu, Yangming; Wang, Qinsheng', 'title' => 'Rapid determination of sulfide in water by flow injection analysis', 'journal' => 'Huanjing Huaxue', 'journal_id' => '0887', 'fadid' => 'HJHX1983V0002P00064', 'year' => '1983', 'volume' => '2', 'issue' => '3', 'startpage' => '64', 'endpage' => '68', 'type' => 'Journal Article', 'analytes' => ';2237;', 'matrices' => ';1079;', 'techniques' => ';0330;', 'keywords' => ';0217;', 'abstract' => 'Sulfide in water was determined by flow injection analysis (FIA) using methylene blue spectrophotometry with a linear calibration for concentrations in the range 3.5-200 mM. The relative standard deviation was 1.05% for 20 determinations of a 56.0 mM S2- sample. Cr(VI) at <0.5 mM shows no interference in the analysis The method can be used to analyze 60-80 samples/h.', 'language' => 'Chinese', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'No', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '0', 'urlcheck' => '2014-10-13 09:59:23', 'urlcheckcode' => 'HTTP/1.1 200 OK', 'pauthor_id' => null, 'pauthor' => 'NA', 'address' => 'Institute of Geography, Academia Sinica, Beijing China', 'email' => 'NA', 'notes' => null, 'url' => 'hjhx.rcees.ac.cn/hjhx/homeAction!downloadArticleFile.action?attachType=PDF&id=3744', 'urltype' => 'pdfurl', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Rapid determination of sulfide in water by flow injection analysis', Huanjing Huaxue, 1983 2(3) 64-68', 'firstchar' => 'R', 'twochars' => 'Ra', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array( [maximum depth reached] ), 'Keyword' => array( [maximum depth reached] ) ), (int) 6 => array( 'id' => '012877', 'authors' => 'Thomas, J.D.R.', 'authorsweb' => 'NA', 'title' => 'Electrochemical analysis of sulfur compounds of environmental interest', 'journal' => 'Int. J. Environ. Anal. Chem.', 'journal_id' => '0734', 'fadid' => 'IEAC1985V0020P00167', 'year' => '1985', 'volume' => '20', 'issue' => '3-4', 'startpage' => '167', 'endpage' => '177', 'type' => 'Journal Article', 'analytes' => ';2237;', 'matrices' => ';0404;1061;0630;', 'techniques' => ';0330;', 'keywords' => ';0217;0389;', 'abstract' => 'A review is presented, largely of work carried out at UWIST, with emphasis on the use of S2--selective electrodes for monitoring industrial liquors (e.g., black liquor) and effluents and sewage effluents and for monitoring the growth of S2--producing bacteria, of importance in the context of industrial spoilage, and also on flow injection analysis with use of ion-selective electrodes and on means of overcoming interference by H2O2. (30 references).', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'No', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '5', 'urlcheck' => '2014-10-12 00:22:14', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => '01339', 'pauthor' => '!Thomas, J.D.R.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1080/03067318508077055', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Electrochemical analysis of sulfur compounds of environmental interest', Int. J. Environ. Anal. 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"Effect Of Membrane Composition On The Flow Injection Response Of An Ion-selective Electrode: A Comparative Study Based An Selectivity Coefficients Calculated Using A Data Linearization Technique"
Electroanalysis
1996 Volume 8, Issue 3 Pages 274-279
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Apparent losses at higher concentration. in the proposed method are ascribed to incorrect sample storage, problems of which are discussed.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '4', 'urlcheck' => '2014-10-11 15:46:39', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => null, 'pauthor' => '!Brunt, K.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1016/S0003-2670(00)81521-4', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Rapid determination of sulfide in waste waters by continuous-flow analysis and gas diffusion and a potentiometric detector', Anal. Chim. 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Thomas', 'title' => 'Studies on flow injection analysis with sulfide ion-selective electrodes', 'journal' => 'Analyst', 'journal_id' => '0864', 'fadid' => 'ANAL1985V0110P00113', 'year' => '1985', 'volume' => '110', 'issue' => '2', 'startpage' => '113', 'endpage' => '119', 'type' => 'Journal Article', 'analytes' => ';2237;', 'matrices' => ';1061;', 'techniques' => ';0330;0400;', 'keywords' => ';0217;0258;', 'abstract' => 'The Orion Model 94-16A, EDT Research EES and EDT Research EES flow-through electrodes were tested and shown to yield near-Nernstian slopes of response between 1 µM and 0.01 M and 0.01 M S2-. Interference by H2O2 can be controlled by adding antioxidant buffer (4% of ascorbic acid in 2 M NaOH). Reconditioning of affected electrodes may be achieved by soaking in 0.1 M Na2S for 48 h and then polishing the membrane surface. For flow injection analysis a carrier stream (2.23 mL min-1) containing 5 µM-Na2S in a medium of 2% of ascorbic acid in 2 M NaOH was suitable for analysis of sewage effluent samples in a 12-cm x 1.3-mm flow tube. For determination of S2- in sewage, flow injection analysis was superior to direct potentiometry. Both the Orion Model 94-16 and EDT Research EES 'flow-through' electrodes yielded values for S2- similar to those obtained colorimetrically. Sulfide contents ranged from 0.1 to 17.8 ppm, the lower level relating to samples pre-treated with H2O2 as a recognized method of controlling adverse sulfidic species in effluent.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '5', 'urlcheck' => '2014-10-12 00:00:39', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => '01339', 'pauthor' => '!Thomas, J.D.R.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1039/an9851000113', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Studies on flow injection analysis with sulfide ion-selective electrodes', Analyst, 1985 110(2) 113-119', 'firstchar' => 'S', 'twochars' => 'St', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array( [maximum depth reached] ), 'Keyword' => array( [maximum depth reached] ) ), (int) 2 => array( 'id' => '007491', 'authors' => 'Van Staden, J.F.', 'authorsweb' => 'Jacobus F. van Staden', 'title' => 'Determination of sulfide using flow injection analysis with a coated tubular solid-state silver-sulfide ion-selective electrode', 'journal' => 'Analyst', 'journal_id' => '0864', 'fadid' => 'ANAL1988V0113P00885', 'year' => '1988', 'volume' => '113', 'issue' => '6', 'startpage' => '885', 'endpage' => '889', 'type' => 'Journal Article', 'analytes' => ';2237;', 'matrices' => ';1061;', 'techniques' => ';0224;0330;0400;', 'keywords' => ';0217;', 'abstract' => 'The electrode described previously (cf., e.g., Anal. Abstr, 1987, 49, 7J12) was activated by deposition of Ag2S as a fine membrane on the inner wall of the tubular cylinder, conditioned for >24 h in 0.1 M Na2S, and incorporated into a flow injection system containing an Orion 90-02 double-junction reference electrode. The performance of the electrode was evaluated by using 1 M KNO3 or sulfide antioxidant buffer solution as carrier stream, and a working range of up to 1 g L-1 was established for determination of S2- (injection volume 30 µL). Results compared favourably with those obtained with a commercial cascade mode electrode, and sensitivity was improved (detection limit 0.4 mg l-1). Mercury, Br-, I-, CN- and S2O32- interfered. The electrode was applied in the determination of S2- in effluents, and the coefficient of variation (n = 15) ranged from 0.9 to 1.8%. Recoveries of S2- added to water ranged from 96 to 104%.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '6', 'urlcheck' => '2014-10-12 00:03:32', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => '00328', 'pauthor' => '!Van Staden, J.F.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1039/an9881300885', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Determination of sulfide using flow injection analysis with a coated tubular solid-state silver-sulfide ion-selective electrode', Analyst, 1988 113(6) 885-889', 'firstchar' => 'D', 'twochars' => 'De', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array( [maximum depth reached] ), 'Keyword' => array( [maximum depth reached] ) ), (int) 3 => array( 'id' => '009912', 'authors' => 'Davey, D.E.;Mulcahy, D.E.;O'Connell, G.R.', 'authorsweb' => 'David E. 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Calibration graphs of the respective ISE responses are presented. Most sensors showed good analytical performance, excepting that prepared from a 3:1 AgI/Ag2S membrane.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '8', 'urlcheck' => '2014-10-11 14:10:51', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => '01201', 'pauthor' => '!O'Connell, G.R.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1002/elan.1140080313', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Effect of membrane composition on the flow injection response of an ion-selective electrode: a comparative study based an selectivity coefficients calculated using a data linearization technique', Electroanalysis, 1996 8(3) 274-279', 'firstchar' => 'E', 'twochars' => 'Ef', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array([maximum depth reached]), 'Keyword' => array( [maximum depth reached] ) ), (int) 4 => array( 'id' => '010806', 'authors' => 'Duffield, E.J.;Moody, G.J.;Thomas, J.D.R.', 'authorsweb' => 'E. Jane Duffield, G. J. Moody, J. D. R. Thomas', 'title' => 'Development of ion-selective electrodes and flow injection analysis for sulfides and thiols', 'journal' => 'Anal. Proc.', 'journal_id' => '0866', 'fadid' => 'ANPR1980V0017P00533', 'year' => '1980', 'volume' => '17', 'issue' => '12', 'startpage' => '533', 'endpage' => '535', 'type' => 'Journal Article', 'analytes' => ';2237;2328;', 'matrices' => 'NA', 'techniques' => ';0330;0127;0213;', 'keywords' => 'NA', 'abstract' => 'The flow injection analysis system was used to control difficulties arising in the response of Ag sulfide membrane ion-selective electrodes to sulfides and thiols due to oxidation and volatility. Reproducible flow injection emf. response peaks were obtained for S2- standards at 10^-4-10-1M.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '2006-08-28 08:56:29', 'hits' => '10', 'urlcheck' => '2014-10-11 21:09:16', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => null, 'pauthor' => 'NA', 'address' => 'NA', 'email' => 'NA', 'notes' => null, 'url' => '10.1039/ap9801700533', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Development of ion-selective electrodes and flow injection analysis for sulfides and thiols', Anal. Proc., 1980 17(12) 533-535', 'firstchar' => 'D', 'twochars' => 'De', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array([maximum depth reached]), 'Keyword' => array([maximum depth reached]) ), (int) 5 => array( 'id' => '012785', 'authors' => 'Wang, L.J.;Zhang, S.;Zhu, Y.M.;Wang, Q.S.', 'authorsweb' => 'Wang, Lijun; Zhang, Shen; Zhu, Yangming; Wang, Qinsheng', 'title' => 'Rapid determination of sulfide in water by flow injection analysis', 'journal' => 'Huanjing Huaxue', 'journal_id' => '0887', 'fadid' => 'HJHX1983V0002P00064', 'year' => '1983', 'volume' => '2', 'issue' => '3', 'startpage' => '64', 'endpage' => '68', 'type' => 'Journal Article', 'analytes' => ';2237;', 'matrices' => ';1079;', 'techniques' => ';0330;', 'keywords' => ';0217;', 'abstract' => 'Sulfide in water was determined by flow injection analysis (FIA) using methylene blue spectrophotometry with a linear calibration for concentrations in the range 3.5-200 mM. The relative standard deviation was 1.05% for 20 determinations of a 56.0 mM S2- sample. Cr(VI) at <0.5 mM shows no interference in the analysis The method can be used to analyze 60-80 samples/h.', 'language' => 'Chinese', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'No', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '0', 'urlcheck' => '2014-10-13 09:59:23', 'urlcheckcode' => 'HTTP/1.1 200 OK', 'pauthor_id' => null, 'pauthor' => 'NA', 'address' => 'Institute of Geography, Academia Sinica, Beijing China', 'email' => 'NA', 'notes' => null, 'url' => 'hjhx.rcees.ac.cn/hjhx/homeAction!downloadArticleFile.action?attachType=PDF&id=3744', 'urltype' => 'pdfurl', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Rapid determination of sulfide in water by flow injection analysis', Huanjing Huaxue, 1983 2(3) 64-68', 'firstchar' => 'R', 'twochars' => 'Ra', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array( [maximum depth reached] ), 'Keyword' => array( [maximum depth reached] ) ), (int) 6 => array( 'id' => '012877', 'authors' => 'Thomas, J.D.R.', 'authorsweb' => 'NA', 'title' => 'Electrochemical analysis of sulfur compounds of environmental interest', 'journal' => 'Int. J. Environ. Anal. Chem.', 'journal_id' => '0734', 'fadid' => 'IEAC1985V0020P00167', 'year' => '1985', 'volume' => '20', 'issue' => '3-4', 'startpage' => '167', 'endpage' => '177', 'type' => 'Journal Article', 'analytes' => ';2237;', 'matrices' => ';0404;1061;0630;', 'techniques' => ';0330;', 'keywords' => ';0217;0389;', 'abstract' => 'A review is presented, largely of work carried out at UWIST, with emphasis on the use of S2--selective electrodes for monitoring industrial liquors (e.g., black liquor) and effluents and sewage effluents and for monitoring the growth of S2--producing bacteria, of importance in the context of industrial spoilage, and also on flow injection analysis with use of ion-selective electrodes and on means of overcoming interference by H2O2. (30 references).', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'No', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '5', 'urlcheck' => '2014-10-12 00:22:14', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => '01339', 'pauthor' => '!Thomas, J.D.R.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1080/03067318508077055', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Electrochemical analysis of sulfur compounds of environmental interest', Int. J. Environ. Anal. Chem., 1985 20(3-4) 167-177', 'firstchar' => 'E', 'twochars' => 'El', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array( [maximum depth reached] ), 'Keyword' => array( [maximum depth reached] ) ) ) ) $c = array( 'id' => '009912', 'authors' => 'Davey, D.E.;Mulcahy, D.E.;O'Connell, G.R.', 'authorsweb' => 'David E. Davey, Dennis E. Mulcahy, Gregory R. 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"Development Of Ion-selective Electrodes And Flow Injection Analysis For Sulfides And Thiols"
Anal. Proc.
1980 Volume 17, Issue 12 Pages 533-535
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D. R. Thomas', 'title' => 'Development of ion-selective electrodes and flow injection analysis for sulfides and thiols', 'journal' => 'Anal. Proc.', 'journal_id' => '0866', 'fadid' => 'ANPR1980V0017P00533', 'year' => '1980', 'volume' => '17', 'issue' => '12', 'startpage' => '533', 'endpage' => '535', 'type' => 'Journal Article', 'analytes' => ';2237;2328;', 'matrices' => 'NA', 'techniques' => ';0330;0127;0213;', 'keywords' => 'NA', 'abstract' => 'The flow injection analysis system was used to control difficulties arising in the response of Ag sulfide membrane ion-selective electrodes to sulfides and thiols due to oxidation and volatility. 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Apparent losses at higher concentration. in the proposed method are ascribed to incorrect sample storage, problems of which are discussed.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '4', 'urlcheck' => '2014-10-11 15:46:39', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => null, 'pauthor' => '!Brunt, K.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1016/S0003-2670(00)81521-4', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Rapid determination of sulfide in waste waters by continuous-flow analysis and gas diffusion and a potentiometric detector', Anal. Chim. Acta, 1984 163(1) 293-297', 'firstchar' => 'R', 'twochars' => 'Ra', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array( [maximum depth reached] ), 'Keyword' => array( [maximum depth reached] ) ), (int) 1 => array( 'id' => '007384', 'authors' => 'Glaister, M.G.;Moody, G.J.;Thomas, J.D.R.', 'authorsweb' => 'M. G. Glaister, G. J. Moody and J. D. R. Thomas', 'title' => 'Studies on flow injection analysis with sulfide ion-selective electrodes', 'journal' => 'Analyst', 'journal_id' => '0864', 'fadid' => 'ANAL1985V0110P00113', 'year' => '1985', 'volume' => '110', 'issue' => '2', 'startpage' => '113', 'endpage' => '119', 'type' => 'Journal Article', 'analytes' => ';2237;', 'matrices' => ';1061;', 'techniques' => ';0330;0400;', 'keywords' => ';0217;0258;', 'abstract' => 'The Orion Model 94-16A, EDT Research EES and EDT Research EES flow-through electrodes were tested and shown to yield near-Nernstian slopes of response between 1 µM and 0.01 M and 0.01 M S2-. Interference by H2O2 can be controlled by adding antioxidant buffer (4% of ascorbic acid in 2 M NaOH). Reconditioning of affected electrodes may be achieved by soaking in 0.1 M Na2S for 48 h and then polishing the membrane surface. For flow injection analysis a carrier stream (2.23 mL min-1) containing 5 µM-Na2S in a medium of 2% of ascorbic acid in 2 M NaOH was suitable for analysis of sewage effluent samples in a 12-cm x 1.3-mm flow tube. For determination of S2- in sewage, flow injection analysis was superior to direct potentiometry. Both the Orion Model 94-16 and EDT Research EES 'flow-through' electrodes yielded values for S2- similar to those obtained colorimetrically. Sulfide contents ranged from 0.1 to 17.8 ppm, the lower level relating to samples pre-treated with H2O2 as a recognized method of controlling adverse sulfidic species in effluent.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '5', 'urlcheck' => '2014-10-12 00:00:39', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => '01339', 'pauthor' => '!Thomas, J.D.R.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1039/an9851000113', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Studies on flow injection analysis with sulfide ion-selective electrodes', Analyst, 1985 110(2) 113-119', 'firstchar' => 'S', 'twochars' => 'St', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array( [maximum depth reached] ), 'Keyword' => array( [maximum depth reached] ) ), (int) 2 => array( 'id' => '007491', 'authors' => 'Van Staden, J.F.', 'authorsweb' => 'Jacobus F. van Staden', 'title' => 'Determination of sulfide using flow injection analysis with a coated tubular solid-state silver-sulfide ion-selective electrode', 'journal' => 'Analyst', 'journal_id' => '0864', 'fadid' => 'ANAL1988V0113P00885', 'year' => '1988', 'volume' => '113', 'issue' => '6', 'startpage' => '885', 'endpage' => '889', 'type' => 'Journal Article', 'analytes' => ';2237;', 'matrices' => ';1061;', 'techniques' => ';0224;0330;0400;', 'keywords' => ';0217;', 'abstract' => 'The electrode described previously (cf., e.g., Anal. Abstr, 1987, 49, 7J12) was activated by deposition of Ag2S as a fine membrane on the inner wall of the tubular cylinder, conditioned for >24 h in 0.1 M Na2S, and incorporated into a flow injection system containing an Orion 90-02 double-junction reference electrode. The performance of the electrode was evaluated by using 1 M KNO3 or sulfide antioxidant buffer solution as carrier stream, and a working range of up to 1 g L-1 was established for determination of S2- (injection volume 30 µL). Results compared favourably with those obtained with a commercial cascade mode electrode, and sensitivity was improved (detection limit 0.4 mg l-1). Mercury, Br-, I-, CN- and S2O32- interfered. The electrode was applied in the determination of S2- in effluents, and the coefficient of variation (n = 15) ranged from 0.9 to 1.8%. Recoveries of S2- added to water ranged from 96 to 104%.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '6', 'urlcheck' => '2014-10-12 00:03:32', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => '00328', 'pauthor' => '!Van Staden, J.F.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1039/an9881300885', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Determination of sulfide using flow injection analysis with a coated tubular solid-state silver-sulfide ion-selective electrode', Analyst, 1988 113(6) 885-889', 'firstchar' => 'D', 'twochars' => 'De', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array( [maximum depth reached] ), 'Keyword' => array( [maximum depth reached] ) ), (int) 3 => array( 'id' => '009912', 'authors' => 'Davey, D.E.;Mulcahy, D.E.;O'Connell, G.R.', 'authorsweb' => 'David E. Davey, Dennis E. Mulcahy, Gregory R. O'Connell*', 'title' => 'Effect of membrane composition on the flow injection response of an ion-selective electrode: a comparative study based an selectivity coefficients calculated using a data linearization technique', 'journal' => 'Electroanalysis', 'journal_id' => '1003', 'fadid' => 'ELAN1996V0008P00274', 'year' => '1996', 'volume' => '8', 'issue' => '3', 'startpage' => '274', 'endpage' => '279', 'type' => 'Journal Article', 'analytes' => ';1275;', 'matrices' => '', 'techniques' => ';0303;0284;0330;0400;', 'keywords' => ';0217;', 'abstract' => 'Portions of 100 µL of iodide solutions containing 100 mM bromide, thiocyanate and thiosulfate as interferents were injected into carrier and reagent streams (total flow 6.6 ml/min) of 1 µM-KI and 100 mM KNO3, and iodide detected using a variety of purpose made AgI/Ag2S (details given) and commercially available iodide, sulfide and cadmium ISE. Calibration graphs of the respective ISE responses are presented. Most sensors showed good analytical performance, excepting that prepared from a 3:1 AgI/Ag2S membrane.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '8', 'urlcheck' => '2014-10-11 14:10:51', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => '01201', 'pauthor' => '!O'Connell, G.R.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1002/elan.1140080313', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Effect of membrane composition on the flow injection response of an ion-selective electrode: a comparative study based an selectivity coefficients calculated using a data linearization technique', Electroanalysis, 1996 8(3) 274-279', 'firstchar' => 'E', 'twochars' => 'Ef', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array([maximum depth reached]), 'Keyword' => array( [maximum depth reached] ) ), (int) 4 => array( 'id' => '010806', 'authors' => 'Duffield, E.J.;Moody, G.J.;Thomas, J.D.R.', 'authorsweb' => 'E. 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J. Environ. Anal. Chem.', 'journal_id' => '0734', 'fadid' => 'IEAC1985V0020P00167', 'year' => '1985', 'volume' => '20', 'issue' => '3-4', 'startpage' => '167', 'endpage' => '177', 'type' => 'Journal Article', 'analytes' => ';2237;', 'matrices' => ';0404;1061;0630;', 'techniques' => ';0330;', 'keywords' => ';0217;0389;', 'abstract' => 'A review is presented, largely of work carried out at UWIST, with emphasis on the use of S2--selective electrodes for monitoring industrial liquors (e.g., black liquor) and effluents and sewage effluents and for monitoring the growth of S2--producing bacteria, of importance in the context of industrial spoilage, and also on flow injection analysis with use of ion-selective electrodes and on means of overcoming interference by H2O2. 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"Rapid Determination Of Sulfide In Water By Flow Injection Analysis"
Huanjing Huaxue
1983 Volume 2, Issue 3 Pages 64-68
Notice (8): Undefined variable: uid [APP/View/Elements/citation.ctp, line 40]Wang, Lijun; Zhang, Shen; Zhu, Yangming; Wang, QinshengCode Context?>
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Brunt', 'title' => 'Rapid determination of sulfide in waste waters by continuous-flow analysis and gas diffusion and a potentiometric detector', 'journal' => 'Anal. Chim. Acta', 'journal_id' => '0584', 'fadid' => 'ANCA1984V0163P00293', 'year' => '1984', 'volume' => '163', 'issue' => '1', 'startpage' => '293', 'endpage' => '297', 'type' => 'Journal Article', 'analytes' => ';2237;', 'matrices' => ';1061;', 'techniques' => ';0330;0400;', 'keywords' => ';0173;0462;', 'abstract' => 'The system is based on a flow-through gaseous diffusion unit and potentiometric determination with a S2--selective electrode. In the range 0.5 to 600 ppm of S2-, the mean response is 30.2 mV per decade. The sampling rate is ~15 h-1, and the efficiency of transfer across the PTFE membrane is 48%. At S2- concentration. <50 ppm, the results obtained agreed well with those by a distillation method. Apparent losses at higher concentration. in the proposed method are ascribed to incorrect sample storage, problems of which are discussed.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '4', 'urlcheck' => '2014-10-11 15:46:39', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => null, 'pauthor' => '!Brunt, K.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1016/S0003-2670(00)81521-4', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Rapid determination of sulfide in waste waters by continuous-flow analysis and gas diffusion and a potentiometric detector', Anal. Chim. Acta, 1984 163(1) 293-297', 'firstchar' => 'R', 'twochars' => 'Ra', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array( [maximum depth reached] ), 'Keyword' => array( [maximum depth reached] ) ), (int) 1 => array( 'id' => '007384', 'authors' => 'Glaister, M.G.;Moody, G.J.;Thomas, J.D.R.', 'authorsweb' => 'M. G. Glaister, G. J. Moody and J. D. R. Thomas', 'title' => 'Studies on flow injection analysis with sulfide ion-selective electrodes', 'journal' => 'Analyst', 'journal_id' => '0864', 'fadid' => 'ANAL1985V0110P00113', 'year' => '1985', 'volume' => '110', 'issue' => '2', 'startpage' => '113', 'endpage' => '119', 'type' => 'Journal Article', 'analytes' => ';2237;', 'matrices' => ';1061;', 'techniques' => ';0330;0400;', 'keywords' => ';0217;0258;', 'abstract' => 'The Orion Model 94-16A, EDT Research EES and EDT Research EES flow-through electrodes were tested and shown to yield near-Nernstian slopes of response between 1 µM and 0.01 M and 0.01 M S2-. Interference by H2O2 can be controlled by adding antioxidant buffer (4% of ascorbic acid in 2 M NaOH). Reconditioning of affected electrodes may be achieved by soaking in 0.1 M Na2S for 48 h and then polishing the membrane surface. For flow injection analysis a carrier stream (2.23 mL min-1) containing 5 µM-Na2S in a medium of 2% of ascorbic acid in 2 M NaOH was suitable for analysis of sewage effluent samples in a 12-cm x 1.3-mm flow tube. For determination of S2- in sewage, flow injection analysis was superior to direct potentiometry. Both the Orion Model 94-16 and EDT Research EES 'flow-through' electrodes yielded values for S2- similar to those obtained colorimetrically. Sulfide contents ranged from 0.1 to 17.8 ppm, the lower level relating to samples pre-treated with H2O2 as a recognized method of controlling adverse sulfidic species in effluent.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '5', 'urlcheck' => '2014-10-12 00:00:39', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => '01339', 'pauthor' => '!Thomas, J.D.R.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1039/an9851000113', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Studies on flow injection analysis with sulfide ion-selective electrodes', Analyst, 1985 110(2) 113-119', 'firstchar' => 'S', 'twochars' => 'St', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array( [maximum depth reached] ), 'Keyword' => array( [maximum depth reached] ) ), (int) 2 => array( 'id' => '007491', 'authors' => 'Van Staden, J.F.', 'authorsweb' => 'Jacobus F. van Staden', 'title' => 'Determination of sulfide using flow injection analysis with a coated tubular solid-state silver-sulfide ion-selective electrode', 'journal' => 'Analyst', 'journal_id' => '0864', 'fadid' => 'ANAL1988V0113P00885', 'year' => '1988', 'volume' => '113', 'issue' => '6', 'startpage' => '885', 'endpage' => '889', 'type' => 'Journal Article', 'analytes' => ';2237;', 'matrices' => ';1061;', 'techniques' => ';0224;0330;0400;', 'keywords' => ';0217;', 'abstract' => 'The electrode described previously (cf., e.g., Anal. Abstr, 1987, 49, 7J12) was activated by deposition of Ag2S as a fine membrane on the inner wall of the tubular cylinder, conditioned for >24 h in 0.1 M Na2S, and incorporated into a flow injection system containing an Orion 90-02 double-junction reference electrode. The performance of the electrode was evaluated by using 1 M KNO3 or sulfide antioxidant buffer solution as carrier stream, and a working range of up to 1 g L-1 was established for determination of S2- (injection volume 30 µL). Results compared favourably with those obtained with a commercial cascade mode electrode, and sensitivity was improved (detection limit 0.4 mg l-1). Mercury, Br-, I-, CN- and S2O32- interfered. The electrode was applied in the determination of S2- in effluents, and the coefficient of variation (n = 15) ranged from 0.9 to 1.8%. Recoveries of S2- added to water ranged from 96 to 104%.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '6', 'urlcheck' => '2014-10-12 00:03:32', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => '00328', 'pauthor' => '!Van Staden, J.F.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1039/an9881300885', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Determination of sulfide using flow injection analysis with a coated tubular solid-state silver-sulfide ion-selective electrode', Analyst, 1988 113(6) 885-889', 'firstchar' => 'D', 'twochars' => 'De', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array( [maximum depth reached] ), 'Keyword' => array( [maximum depth reached] ) ), (int) 3 => array( 'id' => '009912', 'authors' => 'Davey, D.E.;Mulcahy, D.E.;O'Connell, G.R.', 'authorsweb' => 'David E. Davey, Dennis E. Mulcahy, Gregory R. O'Connell*', 'title' => 'Effect of membrane composition on the flow injection response of an ion-selective electrode: a comparative study based an selectivity coefficients calculated using a data linearization technique', 'journal' => 'Electroanalysis', 'journal_id' => '1003', 'fadid' => 'ELAN1996V0008P00274', 'year' => '1996', 'volume' => '8', 'issue' => '3', 'startpage' => '274', 'endpage' => '279', 'type' => 'Journal Article', 'analytes' => ';1275;', 'matrices' => '', 'techniques' => ';0303;0284;0330;0400;', 'keywords' => ';0217;', 'abstract' => 'Portions of 100 µL of iodide solutions containing 100 mM bromide, thiocyanate and thiosulfate as interferents were injected into carrier and reagent streams (total flow 6.6 ml/min) of 1 µM-KI and 100 mM KNO3, and iodide detected using a variety of purpose made AgI/Ag2S (details given) and commercially available iodide, sulfide and cadmium ISE. Calibration graphs of the respective ISE responses are presented. Most sensors showed good analytical performance, excepting that prepared from a 3:1 AgI/Ag2S membrane.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '8', 'urlcheck' => '2014-10-11 14:10:51', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => '01201', 'pauthor' => '!O'Connell, G.R.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1002/elan.1140080313', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Effect of membrane composition on the flow injection response of an ion-selective electrode: a comparative study based an selectivity coefficients calculated using a data linearization technique', Electroanalysis, 1996 8(3) 274-279', 'firstchar' => 'E', 'twochars' => 'Ef', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array([maximum depth reached]), 'Keyword' => array( [maximum depth reached] ) ), (int) 4 => array( 'id' => '010806', 'authors' => 'Duffield, E.J.;Moody, G.J.;Thomas, J.D.R.', 'authorsweb' => 'E. Jane Duffield, G. J. Moody, J. D. R. Thomas', 'title' => 'Development of ion-selective electrodes and flow injection analysis for sulfides and thiols', 'journal' => 'Anal. Proc.', 'journal_id' => '0866', 'fadid' => 'ANPR1980V0017P00533', 'year' => '1980', 'volume' => '17', 'issue' => '12', 'startpage' => '533', 'endpage' => '535', 'type' => 'Journal Article', 'analytes' => ';2237;2328;', 'matrices' => 'NA', 'techniques' => ';0330;0127;0213;', 'keywords' => 'NA', 'abstract' => 'The flow injection analysis system was used to control difficulties arising in the response of Ag sulfide membrane ion-selective electrodes to sulfides and thiols due to oxidation and volatility. Reproducible flow injection emf. response peaks were obtained for S2- standards at 10^-4-10-1M.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '2006-08-28 08:56:29', 'hits' => '10', 'urlcheck' => '2014-10-11 21:09:16', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => null, 'pauthor' => 'NA', 'address' => 'NA', 'email' => 'NA', 'notes' => null, 'url' => '10.1039/ap9801700533', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Development of ion-selective electrodes and flow injection analysis for sulfides and thiols', Anal. Proc., 1980 17(12) 533-535', 'firstchar' => 'D', 'twochars' => 'De', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array([maximum depth reached]), 'Keyword' => array([maximum depth reached]) ), (int) 5 => array( 'id' => '012785', 'authors' => 'Wang, L.J.;Zhang, S.;Zhu, Y.M.;Wang, Q.S.', 'authorsweb' => 'Wang, Lijun; Zhang, Shen; Zhu, Yangming; Wang, Qinsheng', 'title' => 'Rapid determination of sulfide in water by flow injection analysis', 'journal' => 'Huanjing Huaxue', 'journal_id' => '0887', 'fadid' => 'HJHX1983V0002P00064', 'year' => '1983', 'volume' => '2', 'issue' => '3', 'startpage' => '64', 'endpage' => '68', 'type' => 'Journal Article', 'analytes' => ';2237;', 'matrices' => ';1079;', 'techniques' => ';0330;', 'keywords' => ';0217;', 'abstract' => 'Sulfide in water was determined by flow injection analysis (FIA) using methylene blue spectrophotometry with a linear calibration for concentrations in the range 3.5-200 mM. The relative standard deviation was 1.05% for 20 determinations of a 56.0 mM S2- sample. Cr(VI) at <0.5 mM shows no interference in the analysis The method can be used to analyze 60-80 samples/h.', 'language' => 'Chinese', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'No', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '0', 'urlcheck' => '2014-10-13 09:59:23', 'urlcheckcode' => 'HTTP/1.1 200 OK', 'pauthor_id' => null, 'pauthor' => 'NA', 'address' => 'Institute of Geography, Academia Sinica, Beijing China', 'email' => 'NA', 'notes' => null, 'url' => 'hjhx.rcees.ac.cn/hjhx/homeAction!downloadArticleFile.action?attachType=PDF&id=3744', 'urltype' => 'pdfurl', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Rapid determination of sulfide in water by flow injection analysis', Huanjing Huaxue, 1983 2(3) 64-68', 'firstchar' => 'R', 'twochars' => 'Ra', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array( [maximum depth reached] ), 'Keyword' => array( [maximum depth reached] ) ), (int) 6 => array( 'id' => '012877', 'authors' => 'Thomas, J.D.R.', 'authorsweb' => 'NA', 'title' => 'Electrochemical analysis of sulfur compounds of environmental interest', 'journal' => 'Int. 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"Electrochemical Analysis Of Sulfur Compounds Of Environmental Interest"
Int. J. Environ. Anal. Chem.
1985 Volume 20, Issue 3-4 Pages 167-177
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(30 references).', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'No', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '5', 'urlcheck' => '2014-10-12 00:22:14', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => '01339', 'pauthor' => '!Thomas, J.D.R.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1080/03067318508077055', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Electrochemical analysis of sulfur compounds of environmental interest', Int. J. Environ. Anal. Chem., 1985 20(3-4) 167-177', 'firstchar' => 'E', 'twochars' => 'El', 'CitationsTechnique' => array( 'id' => '013164', 'citation_id' => '012877', 'technique_id' => '0330' ), 'Analyte' => array( (int) 0 => array( [maximum depth reached] ) ), 'Matrix' => array( (int) 0 => array( [maximum depth reached] ), (int) 1 => array( [maximum depth reached] ), (int) 2 => array( [maximum depth reached] ) ), 'Keyword' => array( (int) 0 => array( [maximum depth reached] ), (int) 1 => array( [maximum depth reached] ) ) ), 'i' => (int) 6 ) $data = array( 'Technique' => array( 'id' => '0330', 'label' => 'Electrode', 'level1' => 'Electrode', 'level2' => 'ion selective', 'level3' => 'sulfide', 'level4' => '', 'level5' => '', 'synonyms' => 'Ion selective electrode,ISE', 'champ' => '', 'total' => '7', 'updated' => '0000-00-00 00:00:00', 'name' => 'Electrode, ion selective, sulfide', 'nametotal' => 'Electrode, ion selective, sulfide**7', 'first' => 'E' ), 'Citation' => array( (int) 0 => array( 'id' => '004637', 'authors' => 'Brunt, K.', 'authorsweb' => 'K. Brunt', 'title' => 'Rapid determination of sulfide in waste waters by continuous-flow analysis and gas diffusion and a potentiometric detector', 'journal' => 'Anal. Chim. Acta', 'journal_id' => '0584', 'fadid' => 'ANCA1984V0163P00293', 'year' => '1984', 'volume' => '163', 'issue' => '1', 'startpage' => '293', 'endpage' => '297', 'type' => 'Journal Article', 'analytes' => ';2237;', 'matrices' => ';1061;', 'techniques' => ';0330;0400;', 'keywords' => ';0173;0462;', 'abstract' => 'The system is based on a flow-through gaseous diffusion unit and potentiometric determination with a S2--selective electrode. In the range 0.5 to 600 ppm of S2-, the mean response is 30.2 mV per decade. The sampling rate is ~15 h-1, and the efficiency of transfer across the PTFE membrane is 48%. At S2- concentration. <50 ppm, the results obtained agreed well with those by a distillation method. Apparent losses at higher concentration. in the proposed method are ascribed to incorrect sample storage, problems of which are discussed.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '4', 'urlcheck' => '2014-10-11 15:46:39', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => null, 'pauthor' => '!Brunt, K.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1016/S0003-2670(00)81521-4', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Rapid determination of sulfide in waste waters by continuous-flow analysis and gas diffusion and a potentiometric detector', Anal. Chim. Acta, 1984 163(1) 293-297', 'firstchar' => 'R', 'twochars' => 'Ra', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array( [maximum depth reached] ), 'Keyword' => array( [maximum depth reached] ) ), (int) 1 => array( 'id' => '007384', 'authors' => 'Glaister, M.G.;Moody, G.J.;Thomas, J.D.R.', 'authorsweb' => 'M. G. Glaister, G. J. Moody and J. D. R. Thomas', 'title' => 'Studies on flow injection analysis with sulfide ion-selective electrodes', 'journal' => 'Analyst', 'journal_id' => '0864', 'fadid' => 'ANAL1985V0110P00113', 'year' => '1985', 'volume' => '110', 'issue' => '2', 'startpage' => '113', 'endpage' => '119', 'type' => 'Journal Article', 'analytes' => ';2237;', 'matrices' => ';1061;', 'techniques' => ';0330;0400;', 'keywords' => ';0217;0258;', 'abstract' => 'The Orion Model 94-16A, EDT Research EES and EDT Research EES flow-through electrodes were tested and shown to yield near-Nernstian slopes of response between 1 µM and 0.01 M and 0.01 M S2-. Interference by H2O2 can be controlled by adding antioxidant buffer (4% of ascorbic acid in 2 M NaOH). Reconditioning of affected electrodes may be achieved by soaking in 0.1 M Na2S for 48 h and then polishing the membrane surface. For flow injection analysis a carrier stream (2.23 mL min-1) containing 5 µM-Na2S in a medium of 2% of ascorbic acid in 2 M NaOH was suitable for analysis of sewage effluent samples in a 12-cm x 1.3-mm flow tube. For determination of S2- in sewage, flow injection analysis was superior to direct potentiometry. Both the Orion Model 94-16 and EDT Research EES 'flow-through' electrodes yielded values for S2- similar to those obtained colorimetrically. Sulfide contents ranged from 0.1 to 17.8 ppm, the lower level relating to samples pre-treated with H2O2 as a recognized method of controlling adverse sulfidic species in effluent.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '5', 'urlcheck' => '2014-10-12 00:00:39', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => '01339', 'pauthor' => '!Thomas, J.D.R.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1039/an9851000113', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Studies on flow injection analysis with sulfide ion-selective electrodes', Analyst, 1985 110(2) 113-119', 'firstchar' => 'S', 'twochars' => 'St', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array( [maximum depth reached] ), 'Keyword' => array( [maximum depth reached] ) ), (int) 2 => array( 'id' => '007491', 'authors' => 'Van Staden, J.F.', 'authorsweb' => 'Jacobus F. van Staden', 'title' => 'Determination of sulfide using flow injection analysis with a coated tubular solid-state silver-sulfide ion-selective electrode', 'journal' => 'Analyst', 'journal_id' => '0864', 'fadid' => 'ANAL1988V0113P00885', 'year' => '1988', 'volume' => '113', 'issue' => '6', 'startpage' => '885', 'endpage' => '889', 'type' => 'Journal Article', 'analytes' => ';2237;', 'matrices' => ';1061;', 'techniques' => ';0224;0330;0400;', 'keywords' => ';0217;', 'abstract' => 'The electrode described previously (cf., e.g., Anal. Abstr, 1987, 49, 7J12) was activated by deposition of Ag2S as a fine membrane on the inner wall of the tubular cylinder, conditioned for >24 h in 0.1 M Na2S, and incorporated into a flow injection system containing an Orion 90-02 double-junction reference electrode. The performance of the electrode was evaluated by using 1 M KNO3 or sulfide antioxidant buffer solution as carrier stream, and a working range of up to 1 g L-1 was established for determination of S2- (injection volume 30 µL). Results compared favourably with those obtained with a commercial cascade mode electrode, and sensitivity was improved (detection limit 0.4 mg l-1). Mercury, Br-, I-, CN- and S2O32- interfered. The electrode was applied in the determination of S2- in effluents, and the coefficient of variation (n = 15) ranged from 0.9 to 1.8%. Recoveries of S2- added to water ranged from 96 to 104%.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '6', 'urlcheck' => '2014-10-12 00:03:32', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => '00328', 'pauthor' => '!Van Staden, J.F.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1039/an9881300885', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Determination of sulfide using flow injection analysis with a coated tubular solid-state silver-sulfide ion-selective electrode', Analyst, 1988 113(6) 885-889', 'firstchar' => 'D', 'twochars' => 'De', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array( [maximum depth reached] ), 'Keyword' => array( [maximum depth reached] ) ), (int) 3 => array( 'id' => '009912', 'authors' => 'Davey, D.E.;Mulcahy, D.E.;O'Connell, G.R.', 'authorsweb' => 'David E. Davey, Dennis E. Mulcahy, Gregory R. O'Connell*', 'title' => 'Effect of membrane composition on the flow injection response of an ion-selective electrode: a comparative study based an selectivity coefficients calculated using a data linearization technique', 'journal' => 'Electroanalysis', 'journal_id' => '1003', 'fadid' => 'ELAN1996V0008P00274', 'year' => '1996', 'volume' => '8', 'issue' => '3', 'startpage' => '274', 'endpage' => '279', 'type' => 'Journal Article', 'analytes' => ';1275;', 'matrices' => '', 'techniques' => ';0303;0284;0330;0400;', 'keywords' => ';0217;', 'abstract' => 'Portions of 100 µL of iodide solutions containing 100 mM bromide, thiocyanate and thiosulfate as interferents were injected into carrier and reagent streams (total flow 6.6 ml/min) of 1 µM-KI and 100 mM KNO3, and iodide detected using a variety of purpose made AgI/Ag2S (details given) and commercially available iodide, sulfide and cadmium ISE. Calibration graphs of the respective ISE responses are presented. Most sensors showed good analytical performance, excepting that prepared from a 3:1 AgI/Ag2S membrane.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '8', 'urlcheck' => '2014-10-11 14:10:51', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => '01201', 'pauthor' => '!O'Connell, G.R.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1002/elan.1140080313', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Effect of membrane composition on the flow injection response of an ion-selective electrode: a comparative study based an selectivity coefficients calculated using a data linearization technique', Electroanalysis, 1996 8(3) 274-279', 'firstchar' => 'E', 'twochars' => 'Ef', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array([maximum depth reached]), 'Keyword' => array( [maximum depth reached] ) ), (int) 4 => array( 'id' => '010806', 'authors' => 'Duffield, E.J.;Moody, G.J.;Thomas, J.D.R.', 'authorsweb' => 'E. Jane Duffield, G. J. Moody, J. D. R. Thomas', 'title' => 'Development of ion-selective electrodes and flow injection analysis for sulfides and thiols', 'journal' => 'Anal. Proc.', 'journal_id' => '0866', 'fadid' => 'ANPR1980V0017P00533', 'year' => '1980', 'volume' => '17', 'issue' => '12', 'startpage' => '533', 'endpage' => '535', 'type' => 'Journal Article', 'analytes' => ';2237;2328;', 'matrices' => 'NA', 'techniques' => ';0330;0127;0213;', 'keywords' => 'NA', 'abstract' => 'The flow injection analysis system was used to control difficulties arising in the response of Ag sulfide membrane ion-selective electrodes to sulfides and thiols due to oxidation and volatility. Reproducible flow injection emf. response peaks were obtained for S2- standards at 10^-4-10-1M.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '2006-08-28 08:56:29', 'hits' => '10', 'urlcheck' => '2014-10-11 21:09:16', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => null, 'pauthor' => 'NA', 'address' => 'NA', 'email' => 'NA', 'notes' => null, 'url' => '10.1039/ap9801700533', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Development of ion-selective electrodes and flow injection analysis for sulfides and thiols', Anal. Proc., 1980 17(12) 533-535', 'firstchar' => 'D', 'twochars' => 'De', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array([maximum depth reached]), 'Keyword' => array([maximum depth reached]) ), (int) 5 => array( 'id' => '012785', 'authors' => 'Wang, L.J.;Zhang, S.;Zhu, Y.M.;Wang, Q.S.', 'authorsweb' => 'Wang, Lijun; Zhang, Shen; Zhu, Yangming; Wang, Qinsheng', 'title' => 'Rapid determination of sulfide in water by flow injection analysis', 'journal' => 'Huanjing Huaxue', 'journal_id' => '0887', 'fadid' => 'HJHX1983V0002P00064', 'year' => '1983', 'volume' => '2', 'issue' => '3', 'startpage' => '64', 'endpage' => '68', 'type' => 'Journal Article', 'analytes' => ';2237;', 'matrices' => ';1079;', 'techniques' => ';0330;', 'keywords' => ';0217;', 'abstract' => 'Sulfide in water was determined by flow injection analysis (FIA) using methylene blue spectrophotometry with a linear calibration for concentrations in the range 3.5-200 mM. The relative standard deviation was 1.05% for 20 determinations of a 56.0 mM S2- sample. Cr(VI) at <0.5 mM shows no interference in the analysis The method can be used to analyze 60-80 samples/h.', 'language' => 'Chinese', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'No', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '0', 'urlcheck' => '2014-10-13 09:59:23', 'urlcheckcode' => 'HTTP/1.1 200 OK', 'pauthor_id' => null, 'pauthor' => 'NA', 'address' => 'Institute of Geography, Academia Sinica, Beijing China', 'email' => 'NA', 'notes' => null, 'url' => 'hjhx.rcees.ac.cn/hjhx/homeAction!downloadArticleFile.action?attachType=PDF&id=3744', 'urltype' => 'pdfurl', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Rapid determination of sulfide in water by flow injection analysis', Huanjing Huaxue, 1983 2(3) 64-68', 'firstchar' => 'R', 'twochars' => 'Ra', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array( [maximum depth reached] ), 'Keyword' => array( [maximum depth reached] ) ), (int) 6 => array( 'id' => '012877', 'authors' => 'Thomas, J.D.R.', 'authorsweb' => 'NA', 'title' => 'Electrochemical analysis of sulfur compounds of environmental interest', 'journal' => 'Int. J. Environ. Anal. Chem.', 'journal_id' => '0734', 'fadid' => 'IEAC1985V0020P00167', 'year' => '1985', 'volume' => '20', 'issue' => '3-4', 'startpage' => '167', 'endpage' => '177', 'type' => 'Journal Article', 'analytes' => ';2237;', 'matrices' => ';0404;1061;0630;', 'techniques' => ';0330;', 'keywords' => ';0217;0389;', 'abstract' => 'A review is presented, largely of work carried out at UWIST, with emphasis on the use of S2--selective electrodes for monitoring industrial liquors (e.g., black liquor) and effluents and sewage effluents and for monitoring the growth of S2--producing bacteria, of importance in the context of industrial spoilage, and also on flow injection analysis with use of ion-selective electrodes and on means of overcoming interference by H2O2. (30 references).', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'No', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '5', 'urlcheck' => '2014-10-12 00:22:14', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => '01339', 'pauthor' => '!Thomas, J.D.R.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1080/03067318508077055', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Electrochemical analysis of sulfur compounds of environmental interest', Int. J. Environ. Anal. Chem., 1985 20(3-4) 167-177', 'firstchar' => 'E', 'twochars' => 'El', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array( [maximum depth reached] ), 'Keyword' => array( [maximum depth reached] ) ) ) ) $c = array( 'id' => '012877', 'authors' => 'Thomas, J.D.R.', 'authorsweb' => 'NA', 'title' => 'Electrochemical analysis of sulfur compounds of environmental interest', 'journal' => 'Int. J. Environ. Anal. 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(30 references).', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'No', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '5', 'urlcheck' => '2014-10-12 00:22:14', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => '01339', 'pauthor' => '!Thomas, J.D.R.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1080/03067318508077055', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Electrochemical analysis of sulfur compounds of environmental interest', Int. J. Environ. Anal. 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