Contact Info
Stuart Chalk, Ph.D.
Department of Chemistry
University of North Florida
Phone: 1-904-620-1938
Fax: 1-904-620-3535
Email: schalk@unf.edu
Website: @unf
Electrode
Citations 1
"Nickel Oxide Dispersed In A Graphite/poly(vinyl Chloride) Composite Matrix For An Electrocatalytic Amperometric Sensor For Alditols In Flow Injection Analysis"
Anal. Chim. Acta
1995 Volume 307, Issue 1 Pages 43-48
Notice (8): Undefined variable: uid [APP/View/Elements/citation.ctp, line 40]Tommaso R. I. Cataldi* and Diego CentonzeCode Context?><?phpif($uid!='') {$viewFile = '/home/stuchalk/public_html/fad/app/View/Elements/citation.ctp' $dataForView = array( 'data' => array( 'Technique' => array( 'id' => '0118', 'label' => 'Electrode', 'level1' => 'Electrode', 'level2' => 'graphite', 'level3' => 'PVC embedded', 'level4' => '', 'level5' => '', 'synonyms' => '', 'champ' => '', 'total' => '1', 'updated' => '0000-00-00 00:00:00', 'name' => 'Electrode, graphite, PVC embedded', 'nametotal' => 'Electrode, graphite, PVC embedded**1', 'first' => 'E' ), 'Citation' => array( (int) 0 => array( [maximum depth reached] ) ) ), 'c' => array( 'id' => '006118', 'authors' => 'Cataldi, T.R.I.;Centonze, D.', 'authorsweb' => 'Tommaso R. I. Cataldi* and Diego Centonze', 'title' => 'Nickel oxide dispersed in a graphite/poly(vinyl chloride) composite matrix for an electrocatalytic amperometric sensor for alditols in flow injection analysis', 'journal' => 'Anal. Chim. Acta', 'journal_id' => '0584', 'fadid' => 'ANCA1995V0307P00043', 'year' => '1995', 'volume' => '307', 'issue' => '1', 'startpage' => '43', 'endpage' => '48', 'type' => 'Journal Article', 'analytes' => ';0508;0276;0864;1434;1546;2184;2518;', 'matrices' => '', 'techniques' => ';0001;0080;0118;0426;', 'keywords' => ';0067;0167;', 'abstract' => 'A chemically modified electrode was prepared with 50% NiO, 7% PVC and graphite and packing the mixture into a PTFE cavity (4 mm i.d.). The electrode was used in a FIA system for the amperometric detection of alditols. The wall-jet detection cell also had a Ag/AgCl(3 M KCl) reference electrode and a stainless-steel auxiliary electrode; the working electrode was maintained at +0.5 V. The carrier electrolyte (0.5 ml/min) was 0.1 M NaOH and the sample injection volume was 50 µL. Calibration graphs were linear up to 50 mM alditol (or 25 mM sorbitol) and detection limits were 0.02 M for sorbitol, myo-inositol and xylitol, 0.05 M for dulcitol, 0.08 M for mannitol and 0.1 M for D-arabitol. The RSD for 0.5 mM of analyte were 0.8-1.5% (n = 4-6). 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Acta, 1995 307(1) 43-48', 'firstchar' => 'N', 'twochars' => 'Ni', 'CitationsTechnique' => array( 'id' => '002703', 'citation_id' => '006118', 'technique_id' => '0118' ), 'Analyte' => array( (int) 0 => array( [maximum depth reached] ), (int) 1 => array( [maximum depth reached] ), (int) 2 => array( [maximum depth reached] ), (int) 3 => array( [maximum depth reached] ), (int) 4 => array( [maximum depth reached] ), (int) 5 => array( [maximum depth reached] ), (int) 6 => array( [maximum depth reached] ) ), 'Matrix' => array(), 'Keyword' => array( (int) 0 => array( [maximum depth reached] ), (int) 1 => array( [maximum depth reached] ) ) ), 'i' => (int) 0 ) $data = array( 'Technique' => array( 'id' => '0118', 'label' => 'Electrode', 'level1' => 'Electrode', 'level2' => 'graphite', 'level3' => 'PVC embedded', 'level4' => '', 'level5' => '', 'synonyms' => '', 'champ' => '', 'total' => '1', 'updated' => '0000-00-00 00:00:00', 'name' => 'Electrode, graphite, PVC embedded', 'nametotal' => 'Electrode, graphite, PVC embedded**1', 'first' => 'E' ), 'Citation' => array( (int) 0 => array( 'id' => '006118', 'authors' => 'Cataldi, T.R.I.;Centonze, D.', 'authorsweb' => 'Tommaso R. 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The carrier electrolyte (0.5 ml/min) was 0.1 M NaOH and the sample injection volume was 50 µL. Calibration graphs were linear up to 50 mM alditol (or 25 mM sorbitol) and detection limits were 0.02 M for sorbitol, myo-inositol and xylitol, 0.05 M for dulcitol, 0.08 M for mannitol and 0.1 M for D-arabitol. The RSD for 0.5 mM of analyte were 0.8-1.5% (n = 4-6). 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Acta, 1995 307(1) 43-48', 'firstchar' => 'N', 'twochars' => 'Ni', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array([maximum depth reached]), 'Keyword' => array( [maximum depth reached] ) ) ) ) $c = array( 'id' => '006118', 'authors' => 'Cataldi, T.R.I.;Centonze, D.', 'authorsweb' => 'Tommaso R. I. Cataldi* and Diego Centonze', 'title' => 'Nickel oxide dispersed in a graphite/poly(vinyl chloride) composite matrix for an electrocatalytic amperometric sensor for alditols in flow injection analysis', 'journal' => 'Anal. Chim. Acta', 'journal_id' => '0584', 'fadid' => 'ANCA1995V0307P00043', 'year' => '1995', 'volume' => '307', 'issue' => '1', 'startpage' => '43', 'endpage' => '48', 'type' => 'Journal Article', 'analytes' => ';0508;0276;0864;1434;1546;2184;2518;', 'matrices' => '', 'techniques' => ';0001;0080;0118;0426;', 'keywords' => ';0067;0167;', 'abstract' => 'A chemically modified electrode was prepared with 50% NiO, 7% PVC and graphite and packing the mixture into a PTFE cavity (4 mm i.d.). The electrode was used in a FIA system for the amperometric detection of alditols. The wall-jet detection cell also had a Ag/AgCl(3 M KCl) reference electrode and a stainless-steel auxiliary electrode; the working electrode was maintained at +0.5 V. The carrier electrolyte (0.5 ml/min) was 0.1 M NaOH and the sample injection volume was 50 µL. Calibration graphs were linear up to 50 mM alditol (or 25 mM sorbitol) and detection limits were 0.02 M for sorbitol, myo-inositol and xylitol, 0.05 M for dulcitol, 0.08 M for mannitol and 0.1 M for D-arabitol. The RSD for 0.5 mM of analyte were 0.8-1.5% (n = 4-6). The performance of the electrode was stable over 72 h.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '5', 'urlcheck' => '2014-10-11 16:15:23', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => '00909', 'pauthor' => '!Cataldi, T.R.I.', 'address' => 'pau', 'email' => 'pau', 'notes' => null, 'url' => '10.1016/0003-2670(95)00039-3', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Nickel oxide dispersed in a graphite/poly(vinyl chloride) composite matrix for an electrocatalytic amperometric sensor for alditols in flow injection analysis', Anal. Chim. 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'InChI=1S/C5H12O5/c6-1-3(8)5(10)4(9)2-7/h3-10H,1-2H2', 'inchikey' => 'HEBKCHPVOIAQTA-UHFFFAOYSA-N', 'formula' => 'C5H12O5', 'oxstate' => 'Zero', 'url' => '', 'charge' => '0', 'class1' => 'Organic compound', 'class2' => 'NA', 'class3' => 'NA', 'class4' => 'Molecule', 'class5' => '', 'isgroup' => '', 'checked' => 'yes', 'citation_count' => '0', 'updated' => '2015-10-23 09:52:24', 'first' => 'D', 'nametotal' => 'd-Arabitol**1', 'AnalytesCitation' => array( [maximum depth reached] ) ), (int) 2 => array( 'id' => '00864', 'name' => 'Dulcitol', 'iupac_name' => '(2R,3S,4R,5S)-hexane-1,2,3,4,5,6-hexol', 'casrn' => '608-66-2', 'synonyms' => 'D-Dulcitol; Dulcite; Dulcitol; Dulcose; DAG; Euonymit; Melampyrin; Melampyrit; Melampyrite; Melampyrum; Hexitol', 'total' => '1', 'inchi' => 'InChI=1S/C6H14O6/c7-1-3(9)5(11)6(12)4(10)2-8/h3-12H,1-2H2', 'inchikey' => 'FBPFZTCFMRRESA-GUCUJZIJSA-N', 'formula' => ' C6H14O6', 'oxstate' => 'Zero', 'url' => '', 'charge' => '0', 'class1' => 'Organic compound', 'class2' => 'NA', 'class3' => 'NA', 'class4' => 'Molecule', 'class5' => '', 'isgroup' => '', 'checked' => 'yes', 'citation_count' => '0', 'updated' => '2015-10-23 09:57:15', 'first' => 'D', 'nametotal' => 'Dulcitol**1', 'AnalytesCitation' => array( [maximum depth reached] ) ), (int) 3 => array( 'id' => '01434', 'name' => 'd-Mannitol', 'iupac_name' => '(2R,3R,4R,5R)-hexane-1,2,3,4,5,6-hexol', 'casrn' => '69-65-8', 'synonyms' => 'D-mannitol, mannitol, Mannite, Osmitrol, Osmofundin, Manna sugar, 69-65-8, Resectisol, Diosmol, Mannigen, Osmosal, Isotol, Mannit, Cordycepic acid, Mannidex, Mannistol, Invenex, Marine Crystal, Mannitol, D-, Bronchitol, Aridol, Mannogem 2080, Mannitol (VAN), Mannazucker, SDM No. 35, Maniton-S, Mannitol [USAN], Hexahydroxyhexane, CHEBI:16899, Mannidex 16700, NCI-C50362, BRN 1721898, UNII-3OWL53L36A, CCRIS 369, HSDB 714, Mannitol 5%, Mannitol (USP), Mannitol [USP], NSC 9256, (2R,3R,4R,5R)-hexane-1,2,3,4,5,6-hexol, EINECS 200-711-8, EINECS 201-770-2, Mannitol 10%, Mannitol 15%, Mannitol 20%, D-(-)-Mannitol, NSC 407017, NCGC00164246-01, E421, Osmitrol 5% In Water, AI3-19511, Osmitrol 10% In Water, Osmitrol 15% In Water, Osmitrol 20% In Water, DSSTox_CID_3235, MANNITOL 25%, dulcite, manita, DSSTox_RID_76936, DSSTox_GSID_23235, Hexanhexol, Mannitolum, OSMITROL 5% IN WATER IN PLASTIC CONTAINER, OSMITROL 10% IN WATER IN PLASTIC CONTAINER, OSMITROL 15% IN WATER IN PLASTIC CONTAINER, OSMITROL 20% IN WATER IN PLASTIC CONTAINER, Mushroom sugar, D-mannite, Maniton s, Mannit p, Resectisol In Plastic Container, DL-Mannitol, MANNITOL 10% W/ DEXTROSE 5% IN DISTILLED WATER, 1,2,3,4,5,6-Hexanehexol, Mannitol 5% In Plastic Container, Mannitol 10% In Plastic Container, Mannitol 15% In Plastic Container, MANNITOL 15% W/ DEXTROSE 5% IN SODIUM CHLORIDE 0.45%, Mannitol 20% In Plastic Container, MANNITOL 5% W/ DEXTROSE 5% IN SODIUM CHLORIDE 0.12%, Osmitrol (TN), 87-78-5, CAS-69-65-8, 85085-15-0, MTL, D-Mannitol, Mannitol, Osmitrol, Osmofundin, bmse000099, CHEMBL689, Ambap69-65-8, MLS001335977, MLS001335978, 15719_ALDRICH, M1902_SIGMA, 15719_RIEDEL, 33440_RIEDEL, AC1L1M49, AC1Q28E5, M4125_SIAL, M8429_SIAL, M9546_SIAL, M9647_SIAL, 33440_SIGMA, 63559_FLUKA, 63559_SIGMA, 63560_FLUKA, 63565_FLUKA, 63565_SIGMA, C6H14O6, Cordycepate, Deltamannit, MolPort-003-927-039, Osmosteril, Demanitol, Diurecide, Fraxinine, Manitol, Maniton, Mannisol, Osmohale, Osmosol, Manit, D-mitobronitol, Manitol Mein, Mannit-Losung, AR-1J3861, Mannisol A, ZINC02041302, cpd without stereochemical designation, 1,2,3,4,5,6-Hexahexol, Mannite, Mannite Actipharm, LS-1588, (D)-mannitol, AC-12776, LS-89250, SMR000857324, TL806434, AB1002081, M0044, S2381_Selleck, C00392, D00062, D-Mannitol (JP16), 4-01-00-02841 (Beilstein Handbook Reference), ED1D1E61-FEFB-430A-AFDC-D1F4A957FC3D, SCHEMBL919, Epitope ID:114705, 3OWL53L36A, HMDB00765, FBPFZTCFMRRESA-KVTDHHQDSA-N, HMS2230N11, 123897-58-5, 133-43-7, 36413-61-3, 5149-40-6, 75398-80-0, HY-N0378, Tox21_112092, Tox21_201487, Tox21_300483, AKOS006280947, Tox21_112092_1, BCP9000575, CS-2494, DB00742, RP24311, D-Mannito-Supplied by Selleck Chemicals, NCGC00164246-03, NCGC00164246-04, NCGC00164246-05, NCGC00254277-01, NCGC00259038-01, AJ-33305, AK-48449, AN-23785, CJ-32570, K167, KB-53490, SC-18306, WURCS=1.0/1,0/[h1122h], AB0008020, KB-251717, E 421, E-421, FT-0625542, 1630-EP2269989A1, 1630-EP2269994A1, 1630-EP2269996A1, 1630-EP2269999A1, 1630-EP2270000A1, 1630-EP2270002A1, 1630-EP2270005A1, 1630-EP2270007A1, 1630-EP2270008A1, 1630-EP2270011A1, 1630-EP2270012A1, 1630-EP2270013A1, 1630-EP2270014A1, 1630-EP2272517A1, 1630-EP2272537A2, 1630-EP2272817A1, 1630-EP2272826A1, 1630-EP2272848A1, 1630-EP2275412A1, 1630-EP2275413A1, 1630-EP2275420A1, 1630-EP2275421A1, 1630-EP2277507A1, 1630-EP2277565A2, 1630-EP2277566A2, 1630-EP2277567A1, 1630-EP2277568A2, 1630-EP2277569A2, 1630-EP2277570A2, 1630-EP2277861A1, 1630-EP2277867A2, 1630-EP2277877A1, 1630-EP2277879A1, 1630-EP2280003A2, 1630-EP2280008A2, 1630-EP2280010A2, 1630-EP2281559A1, 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1630-EP2311837A1, 1630-EP2311838A1, 1630-EP2311840A1, 1630-EP2311842A2, 1630-EP2314295A1, 1630-EP2314575A1, 1630-EP2314584A1, 1630-EP2314586A1, 1630-EP2314590A1, 1630-EP2314591A1, 1630-EP2314593A1, 1630-EP2316470A2, 1630-EP2316829A1, 1630-EP2316831A1, 1630-EP2316832A1, 1630-EP2316833A1, 1630-EP2316834A1, 1630-EP2316836A1, 1630-EP2371811A2, 1630-EP2374454A1, 1630-EP2374790A1, 1630-EP2374792A1, 1630-EP2377849A2, X-3269, 27808-EP2269993A1, 27808-EP2270505A1, 27808-EP2277874A1, 27808-EP2277880A1, 27808-EP2281823A2, 27808-EP2284160A1, 27808-EP2287155A1, 27808-EP2292610A1, 27808-EP2292612A2, 27808-EP2295406A1, 27808-EP2295414A1, 27808-EP2295432A1, 27808-EP2298731A1, 27808-EP2298767A1, 27808-EP2298772A1, 27808-EP2301938A1, 27808-EP2305219A1, 27808-EP2308839A1, 27808-EP2311822A1, 27808-EP2314587A1, (2R,3R,4R,5R)-Hexane-1,2,3,4,5,6-hexaol', 'total' => '4', 'inchi' => 'InChI=1S/C6H14O6/c7-1-3(9)5(11)6(12)4(10)2-8/h3-12H,1-2H2', 'inchikey' => 'FBPFZTCFMRRESA-KVTDHHQDSA-N', 'formula' => 'C6H14O6', 'oxstate' => 'Zero', 'url' => '', 'charge' => '0', 'class1' => '', 'class2' => '', 'class3' => '', 'class4' => '', 'class5' => '', 'isgroup' => 'no', 'checked' => 'no', 'citation_count' => '0', 'updated' => '2015-10-23 21:31:15', 'first' => 'D', 'nametotal' => 'd-Mannitol**4', 'AnalytesCitation' => array( [maximum depth reached] ) ), (int) 4 => array( 'id' => '01546', 'name' => 'Myo-inositol', 'iupac_name' => 'cyclohexane-1,2,3,4,5,6-hexol', 'casrn' => '87-89-8', 'synonyms' => 'myo-inositol, inositol, Scyllo-inositol, meso-Inositol, Muco-Inositol, i-Inositol, epi-Inositol, Allo-inositol, Myoinositol, Scyllitol, Dambose, Meat sugar, mesoinositol, Phaseomannite, Myoinosite, Quercinitol, Iso-inositol, Phaseomannitol, Inosital, Inositene, Inositina, Mesoinosit, Mesoinosite, Scyllite, Inosite, Mesovit, Nucite, Mesol, cyclohexane-1,2,3,4,5,6-hexol, Cyclohexitol, Cocositol, 1D-Chiro-inositol, 1L-Chiro-inositol, Cyclohexanehexol, D-(+)-chiro-Inositol, 87-89-8, D-myo-Inositol, Inositol, meso-, Inositol, myo-, 488-59-5, chiro-inositol, cis-Inositol, D-chiro-Inositol, cis-1,2,3,5-trans-4,6-Cyclohexanehexol, 643-12-9, 6917-35-7, Bios I, Cyclohexane-1,2,3,4,5,6-hexaol, Isoinositol, Insitolum, Neo-inositol, L-myo-Inositol, D-chiro Inositol, Inositol, muco-, L-chiro-Inositol, 1D-myo-Inositol, 1L-myo-Inositol, Inositol, i-, Inositol (VAN), L-Inositol, Inositol, allo-, Inositol, epi-, Inositol, scyllo-, Rat antispectacled eye factor, (-)-Inositol, Hexahydroxycyclohexane, CCRIS 6745, 551-72-4, CHEBI:17268, NSC8101, 1,2,3,4,5,6-cyclohexanhexol, L-(-)-chiro-Inositol, 1,2,3,5-trans-4,6-Cyclohexanehexol, cis-, Mouse antialopecia factor, NSC404118, Inositol, myo- (8CI), 488-58-4, 1,3,5/2,4,6-Hexahydroxycyclohexane, AI3-16111, (1r,2r,3r,4r,5r,6r)-cyclohexane-1,2,3,4,5,6-hexol, I5125_SIAL, (1R,2R,3S,4S,5S,6S)-cyclohexane-1,2,3,4,5,6-hexol, MI, myo -Inositol, CHEBI:10642, CHEBI:23927, CHEBI:27372, CHEBI:27987, AZD 103, 1,2,3,4,5,6-HEXAHYDROXY-CYCLOHEXANE, CDAISMWEOUEBRE-CDRYSYESSA-N, 1,2,3,4,5,6-Cyclohexanehexol, 1,2,3,5/4,6-Cyclohexanehexol, 1,3,5/2,4,6-cyclohexanehexol, UNII-4L6452S749, Inositol (VAN8C, NSC 8101, NSC45517, NSC55551, NSC55552, EINECS 201-781-2, 1,2,3,4,5,6-Hexahydroxycyclohexane, 1,2,3,5/4,6-Hexahydroxycyclohexane, 1,2,4/3,5,6-Hexahydroxycyclohexane, NSC 404118, 488-55-1, 643-10-7, INS, NCGC00159409-02, (1r,2R,3S,4s,5R,6S)-cyclohexane-1,2,3,4,5,6-hexol, myo-Inositol-(2-3H), ST50406013, DSSTox_CID_3146, DSSTox_RID_76890, DSSTox_GSID_23146, 41546-34-3, 1,3,4,5,6-Cyclohexanehexol, 1,3,5/4,6-Cyclohexanehexol, (1R,2R,3R,4R,5S,6S)-cyclohexane-1,2,3,4,5,6-hexol, (1r,2R,3R,4s,5S,6S)-cyclohexane-1,2,3,4,5,6-hexol, (1r,2R,3S,4r,5R,6S)-cyclohexane-1,2,3,4,5,6-hexol, 1,2,4/3,5,6-cyclohexanehexol, 1,2,3,4,5,6-Cyclohexanehexol #, CAS-87-89-8, cis-1,3,5-trans-4,6-Cyclohexanehexol, 173524-45-3, 38876-99-2, 576-63-6, SMR000857145, SMR000857319, SMR000857320, inositols, Muscle sugar, 4irx, Inositol, chiro-, Inosital (TN), Inositol (DCF), Inositol [NF], CBU, epi-Cyclohexanehexol, (+)-Inositol, 1-L-chiro-Inositol, EPIINOSITOL, (+)-Epi-Inositol, (-)-chiro-Inositol, AmbotzGBB1246, (+)-Chiro-Inositol, scyllo-Cyclohexanehexol, INOSITOL, MESO, Spectrum_001595, 2os9, Cyclohexanehexol;Inositol, AC1Q2AJJ, INOSITOL (D), INOSITOL (L), Spectrum3_001053, Spectrum4_001193, Spectrum5_000961, bmse000102, bmse000103, bmse000113, bmse000901, bmse000922, Epitope ID:144993, AC1L1A9E, D- -CHIRO-INOSITOL, SCHEMBL5831, SCHEMBL5832, SCHEMBL5969, NCIOpen2_008191, BSPBio_002606, KBioGR_001885, KBioSS_002075, KSC225S4P, MLS001332377, MLS001332378, MLS001335965, MLS001335966, MLS001335967, MLS001335968, Ambap6917-35-7, I0269_SIGMA, I0527_SIGMA, I3011_SIGMA, I5125_SIGMA, I7508_SIGMA, I8132_SIGMA, SCHEMBL187278, SCHEMBL187397, SCHEMBL187796, SCHEMBL188106, SCHEMBL188237, SCHEMBL491333, SCHEMBL959404, SCHEMBL959405, 468045_ALDRICH, 468053_ALDRICH, 468061_ALDRICH, 468088_ALDRICH, CHEMBL122705, CHEMBL278373, CHEMBL279736, CHEMBL468154, GTPL4495, GTPL4645, GTPL4648, GTPL4649, MEGxp0_001817, SCHEMBL1055883, SCHEMBL4748543, SCHEMBL6378921, SCHEMBL6468882, SCHEMBL6791918, CHEMBL1222251, CHEMBL1231671, CHEMBL1950780, SCHEMBL12371461, SCHEMBL12377889, SCHEMBL12411898, SCHEMBL12711208, SCHEMBL12735687, SCHEMBL13058696, SCHEMBL13114115, SCHEMBL13114116, SCHEMBL13114128, SCHEMBL13207905, SCHEMBL13580047, SCHEMBL14542470, UNII-1VS4X81277, 57569_FLUKA, 57569_SIGMA, 57570_FLUKA, ACon1_002457, CHEBI:22357, CHEBI:23311, CHEBI:24848, CHEBI:25492, CHEBI:27374, CTK1C5947, CTK8B3795, HMDB00211, HMDB06088, KBio2_002075, KBio2_004643, KBio2_007211, KBio3_001826, C6H12O6, CDAISMWEOUEBRE-GNIYUCBRSA-N, CDAISMWEOUEBRE-GPIVLXJGSA-N, CDAISMWEOUEBRE-LOLGQZEGSA-N, CDAISMWEOUEBRE-NIPYSYMMSA-N, CDAISMWEOUEBRE-OQYPVSDDSA-N, CDAISMWEOUEBRE-UHFFFAOYSA-N, MolPort-001-742-552, MolPort-001-785-905, MolPort-003-719-862, MolPort-003-848-190, MolPort-003-933-929, MolPort-008-267-886, 1,2,3,4,5/6-cyclohexanehexol, 1,2,3,4/5,6-cyclohexanehexol, 1,2,3/4,5,6-cyclohexanehexol, 1,2,4,5/3,6-cyclohexanehexol, HMS2091N13, HMS2230N03, HMS2235H05, HMS2235M23, HMS3369B06, HMS3369F20, HMS3373E05, KST-1B9360, Pharmakon1600-01500352, (1/4) inverted exclamation markIC, NSC-8101, NSC25142, NSC55558, EINECS 207-681-5, EINECS 207-682-0, EINECS 209-000-7, EINECS 211-393-5, EINECS 211-394-0, EINECS 230-024-9, Tox21_111642, Tox21_302035, 6643AB, ANW-43204, AR-1B5044, CC-093, CCG-36096, DNC000974, KM0846, NSC 25142, NSC-25142, NSC-45517, NSC-55551, NSC-55552, NSC-55558, NSC103959, NSC127230, NSC757076, ZINC01530357, 1,2,3,4,5,6/0-cyclohexanetetrol, AKOS006240678, AKOS006332036, AKOS015895894, AKOS015912905, AKOS015912934, AKOS015960429, AKOS015960633, AKOS015994742, AKOS024318869, Tox21_111642_1, 1VS4X81277, DB03106, KS-1284, KS-1420, LS-2350, MCULE-2727773046, NSC-103959, NSC-127230, NSC-404118, NSC-757076, RP24128, TRA0065469, VC30505, TRA-0204644, NCGC00159409-03, NCGC00159409-04, NCGC00169828-01, NCGC00178580-01, NCGC00178580-03, NCGC00255362-01, AC-11070, AJ-26654, AK102790, AK115152, AN-18118, AN-23658, AN-24133, CJ-05199, CJ-23964, K572, NCI60_041778, SC-18136, AB0014290, KB-251247, KB-296111, NP-010162, TL8004550, TL8004551, TR-016439, TR-017741, TR-019452, TR-022051, TR-022053, 4CH-024633, 4L6452S749, FT-0627237, FT-0632208, FT-0632209, FT-0632730, FT-0652045, FT-0670357, FT-0693444, FT-0693614, I0040, I0628, I0629, I0630, I0631, I0632, I0633, LT03328768, ST24024704, ST24049158, (1R)-Cyclohexane-1r,2c,3t,4c,5t,6t-hexaol, 3635-EP2275412A1, 3635-EP2280282A1, 3635-EP2289886A1, 3635-EP2292088A1, 3635-EP2295417A1, 3635-EP2295437A1, 3635-EP2298312A1, 3635-EP2298775A1, 3635-EP2305636A1, 3635-EP2305677A1, 3635-EP2305682A1, 3635-EP2308879A1, C00137, C06152, C06153, C19891, D08079, I-6500, K-9876, meso-(1/4) inverted exclamation mark (1/4), 12513-EP2277880A1, 12513-EP2277881A1, 12513-EP2292597A1, 12513-EP2292610A1, 12513-EP2298744A2, 12513-EP2298768A1, 12513-EP2305825A1, 12513-EP2316831A1, 12513-EP2374790A1, 13719-EP2269977A2, 13719-EP2280010A2, 13719-EP2289891A2, 13719-EP2295437A1, 13719-EP2298734A2, 13719-EP2298775A1, 13719-EP2308875A1, 13719-EP2311831A1, 13719-EP2316836A1, 40032-EP2298312A1, 40032-EP2311830A1, A834712, A836375, I06-1350, I14-2742, Scyllite (for the structural isomer scyllo-Inositol), 7B0CEF84-D9CE-4A88-AA7D-EC50C89387A5, I14-47229, I14-47230, I14-47231, I14-47232, I14-60538, 1D7A27BF-6060-4FA9-AC46-3BD18DBA406E, 220128F1-89BF-442D-AD6D-E6D1EA7BA625, 3B3-016478, 3B3-024034, 3B3-029086, 3B3-070415, 3B3-078032, I14-101844, (1R,2S,3S,4R,5S,6r)-cyclohexane-1,2,3,4,5,6-hexol, (1s,2R,3R,4s,5S,6S)-cyclohexane-1,2,3,4,5,6-hexol, (1s,2s,3s,4s,5s,6s)-cyclohexane-1,2,3,4,5,6-hexol, (1R,2R,3S,4R,5S,6S)-cyclohexane-1,2,3,4,5,6-hexol, 1,2,3,4,5,6-Cyclohexanehexol, (cis,cis,cis,trans,cis,trans)- #, 1,2,3,4,5,6-cyclohexanehexol, (1α,2α,3α,4beta,5α,6beta), 2H3, 488-54-0, 53319-35-0', 'total' => '2', 'inchi' => 'InChI=1S/C6H12O6/c7-1-2(8)4(10)6(12)5(11)3(1)9/h1-12H', 'inchikey' => 'CDAISMWEOUEBRE-UHFFFAOYSA-N', 'formula' => 'C6H12O6', 'oxstate' => 'Zero', 'url' => '', 'charge' => '0', 'class1' => '', 'class2' => '', 'class3' => '', 'class4' => '', 'class5' => '', 'isgroup' => 'no', 'checked' => 'no', 'citation_count' => '0', 'updated' => '2015-12-11 16:11:47', 'first' => 'M', 'nametotal' => 'Myo-inositol**2', 'AnalytesCitation' => array( [maximum depth reached] ) ), (int) 5 => array( 'id' => '02184', 'name' => 'Sorbitol', 'iupac_name' => '(2R,3R,4R,5S)-hexane-1,2,3,4,5,6-hexol', 'casrn' => '50-70-4', 'synonyms' => 'D-glucitol; Diakarmon; Glucitol; L-gulitol; D-1,2,3,4,5,6-hexanehexol; Nivitin; Sionit; Sionon; Sorbicolan; Sorbite; D-sorbitol; Sorbo; Sorbol; component of Probilagol; Cholaxine; D-Sorbol; Esasorb; Glucitol, D-; Gulitol; Karion; Neosorb; Sionite; Siosan; Sorbex M; Sorbex R; Sorbex Rp; Sorbex S; Sorbex X; Sorbilande; Sorbit; Sorbitol syrup C; Sorbostyl; Sorvilande; Syn M.D.; Sorbitol, (d); A-625/641ABS 301K; A-625/641ABS 500FR-1; Cystosol; d-Galactitol; d-Sorbit; d-Sorbite; Hexahydric alcohol; Hydex 100 gran.206; Karion, sionit; Liponic 70-NC; Orbit; Resulax; Sorban; Sorbelite C; Sorbilax; Sorbitol (EGIC); Sorbitur; Sorbostryl; Hexitol', 'total' => '5', 'inchi' => 'InChI=1S/C6H14O6/c7-1-3(9)5(11)6(12)4(10)2-8/h3-12H,1-2H2', 'inchikey' => 'FBPFZTCFMRRESA-JGWLITMVSA-N', 'formula' => ' C6H14O6', 'oxstate' => 'Zero', 'url' => '', 'charge' => '0', 'class1' => 'Organic compound', 'class2' => 'NA', 'class3' => 'NA', 'class4' => 'Molecule', 'class5' => 'Sugars', 'isgroup' => '', 'checked' => 'yes', 'citation_count' => '0', 'updated' => '2015-12-11 16:18:02', 'first' => 'S', 'nametotal' => 'Sorbitol**5', 'AnalytesCitation' => array( [maximum depth reached] ) ), (int) 6 => array( 'id' => '02518', 'name' => 'Xylitol', 'iupac_name' => '(2S,4R)-pentane-1,2,3,4,5-pentol', 'casrn' => '87-99-0', 'synonyms' => 'Xylite; Klinit; Pentitol', 'total' => '2', 'inchi' => 'InChI=1S/C5H12O5/c6-1-3(8)5(10)4(9)2-7/h3-10H,1-2H2', 'inchikey' => 'HEBKCHPVOIAQTA-NGQZWQHPSA-N', 'formula' => 'C5H12O5', 'oxstate' => 'Zero', 'url' => '', 'charge' => '0', 'class1' => 'Organic compound', 'class2' => 'NA', 'class3' => 'NA', 'class4' => 'Molecule', 'class5' => '', 'isgroup' => '', 'checked' => 'yes', 'citation_count' => '0', 'updated' => '2015-10-23 21:39:53', 'first' => 'X', 'nametotal' => 'Xylitol**2', 'AnalytesCitation' => array( [maximum depth reached] ) ) ), 'Matrix' => array(), 'Keyword' => array( (int) 0 => array( 'id' => '0067', 'type' => 'Manifold process', 'keyword' => 'Catalysis', 'newKeyword' => '', 'synonyms' => '', 'fao' => '', 'total' => '337', 'first' => 'C', 'keytotal' => 'Catalysis**337', 'CitationsKeyword' => array( [maximum depth reached] ) ), (int) 1 => array( 'id' => '0167', 'type' => 'Manifold component', 'keyword' => 'Flowcell', 'newKeyword' => '', 'synonyms' => '', 'fao' => '', 'total' => '156', 'first' => 'F', 'keytotal' => 'Flowcell**156', 'CitationsKeyword' => array( [maximum depth reached] ) ) ) ) $i = (int) 0 $path = '' $a = '' $url = 'http://dx.doi.org/10.1016/0003-2670(95)00039-3' $aus = 'Tommaso R. I. Cataldi* and Diego Centonze'include - APP/View/Elements/citation.ctp, line 40 View::_evaluate() - CORE/Cake/View/View.php, line 971 View::_render() - CORE/Cake/View/View.php, line 933 View::_renderElement() - CORE/Cake/View/View.php, line 1224 View::element() - CORE/Cake/View/View.php, line 418 include - APP/View/Techniques/view.ctp, line 52 View::_evaluate() - CORE/Cake/View/View.php, line 971 View::_render() - CORE/Cake/View/View.php, line 933 View::render() - CORE/Cake/View/View.php, line 473 Controller::render() - CORE/Cake/Controller/Controller.php, line 968 Dispatcher::_invoke() - CORE/Cake/Routing/Dispatcher.php, line 200 Dispatcher::dispatch() - CORE/Cake/Routing/Dispatcher.php, line 167 [main] - APP/webroot/index.php, line 109
Abstract:
A chemically modified electrode was prepared with 50% NiO, 7% PVC and graphite and packing the mixture into a PTFE cavity (4 mm i.d.). The electrode was used in a FIA system for the amperometric detection of alditols. The wall-jet detection cell also had a Ag/AgCl(3 M KCl) reference electrode and a stainless-steel auxiliary electrode; the working electrode was maintained at +0.5 V. The carrier electrolyte (0.5 ml/min) was 0.1 M NaOH and the sample injection volume was 50 µL. Calibration graphs were linear up to 50 mM alditol (or 25 mM sorbitol) and detection limits were 0.02 M for sorbitol, myo-inositol and xylitol, 0.05 M for dulcitol, 0.08 M for mannitol and 0.1 M for D-arabitol. The RSD for 0.5 mM of analyte were 0.8-1.5% (n = 4-6). The performance of the electrode was stable over 72 h.
Carbohydrates
d-Arabitol
Dulcitol
d-Mannitol
Myo-inositol
Sorbitol
Xylitol
Catalysis
Flowcell