"Electrostatically Assembled Films For Improving The Properties Of Tetraruthenated Porphyrin-modified Electrodes"
Electroanalysis
1998 Volume 10, Issue 7 Pages 467-471
Notice (8): Undefined variable: uid [APP/View/Elements/citation.ctp, line 40]Code Context ?>
<?php
if($uid!='') {
$viewFile = '/home/stuchalk/public_html/fad/app/View/Elements/citation.ctp'
$dataForView = array(
'data' => array(
'Technique' => array(
'id' => '0093',
'label' => 'Electrode',
'level1' => 'Electrode',
'level2' => 'film',
'level3' => '',
'level4' => '',
'level5' => '',
'synonyms' => '',
'champ' => '',
'total' => '1',
'updated' => '0000-00-00 00:00:00',
'name' => 'Electrode, film',
'nametotal' => 'Electrode, film**1',
'first' => 'E'
),
'Citation' => array(
(int) 0 => array(
[maximum depth reached]
)
)
),
'c' => array(
'id' => '009970',
'authors' => 'Azevedo, C.M.N.;Araki, K.;Angnes, L.;Toma, H.E.',
'authorsweb' => 'Carla M.N. Azevedo, Koiti Araki, Lúcio Angnes, Henrique E. Toma',
'title' => 'Electrostatically assembled films for improving the properties of tetraruthenated porphyrin-modified electrodes',
'journal' => 'Electroanalysis',
'journal_id' => '1003',
'fadid' => 'ELAN1998V0010P00467',
'year' => '1998',
'volume' => '10',
'issue' => '7',
'startpage' => '467',
'endpage' => '471',
'type' => 'Journal Article',
'analytes' => ';2242;1592;',
'matrices' => '',
'techniques' => ';0001;0093;0127;',
'keywords' => ';0043;0110;',
'abstract' => 'Modified electrodes, suitable for use in flow injection anal., were obtained by the electrostatic assembly of films constituted by 2 different porphyrins, namely, µ-meso(tetrapyridyl)porphyrinatecobalt(III)tetrakis[bis(bipyridine)(chloro)ruthenium(II)] and meso-tetra(4-sulfonatephenyl)porphyrinatezinc(II), forming alternating layers onto glassy carbon surfaces. The films were studied by cyclic voltammetry and proved to be strongly adherent and highly stable. They could be used for at least a week without loss of sensitivity. In addition, they exhibit an enhanced amperometric response and good protection against fouling, e.g., by phenol oxidation products. Their usefulness in flow injection analysis of NO2- and SO32- was demonstrated. Excellent signal to noise ratios were obtained for SO32- down to 10^-6 mol/L, and for NO2- down to 10^-7 mol/L.',
'language' => 'English',
'updated' => '2020-12-28 11:25:15',
'sjccheck' => 'Yes',
'sjccheckdate' => '0000-00-00 00:00:00',
'hits' => '17',
'urlcheck' => '2014-10-11 14:12:28',
'urlcheckcode' => 'HTTP/1.1 302 Found',
'pauthor_id' => '01348',
'pauthor' => '!Toma, H.E.',
'address' => 'pau',
'email' => 'pau',
'notes' => null,
'url' => '10.1002/(SICI)1521-4109(199806)10:7<467::AID-ELAN467>3.0.CO;2-W',
'urltype' => 'doi',
'gotpdf' => 'yes',
'partial' => 'no',
'notanalyte' => '',
'citation' => ''Electrostatically assembled films for improving the properties of tetraruthenated porphyrin-modified electrodes', Electroanalysis, 1998 10(7) 467-471',
'firstchar' => 'E',
'twochars' => 'El',
'CitationsTechnique' => array(
'id' => '008737',
'citation_id' => '009970',
'technique_id' => '0093'
),
'Analyte' => array(
(int) 0 => array(
[maximum depth reached]
),
(int) 1 => array(
[maximum depth reached]
)
),
'Matrix' => array(),
'Keyword' => array(
(int) 0 => array(
[maximum depth reached]
),
(int) 1 => array(
[maximum depth reached]
)
)
),
'i' => (int) 0
)
$data = array(
'Technique' => array(
'id' => '0093',
'label' => 'Electrode',
'level1' => 'Electrode',
'level2' => 'film',
'level3' => '',
'level4' => '',
'level5' => '',
'synonyms' => '',
'champ' => '',
'total' => '1',
'updated' => '0000-00-00 00:00:00',
'name' => 'Electrode, film',
'nametotal' => 'Electrode, film**1',
'first' => 'E'
),
'Citation' => array(
(int) 0 => array(
'id' => '009970',
'authors' => 'Azevedo, C.M.N.;Araki, K.;Angnes, L.;Toma, H.E.',
'authorsweb' => 'Carla M.N. Azevedo, Koiti Araki, Lúcio Angnes, Henrique E. Toma',
'title' => 'Electrostatically assembled films for improving the properties of tetraruthenated porphyrin-modified electrodes',
'journal' => 'Electroanalysis',
'journal_id' => '1003',
'fadid' => 'ELAN1998V0010P00467',
'year' => '1998',
'volume' => '10',
'issue' => '7',
'startpage' => '467',
'endpage' => '471',
'type' => 'Journal Article',
'analytes' => ';2242;1592;',
'matrices' => '',
'techniques' => ';0001;0093;0127;',
'keywords' => ';0043;0110;',
'abstract' => 'Modified electrodes, suitable for use in flow injection anal., were obtained by the electrostatic assembly of films constituted by 2 different porphyrins, namely, µ-meso(tetrapyridyl)porphyrinatecobalt(III)tetrakis[bis(bipyridine)(chloro)ruthenium(II)] and meso-tetra(4-sulfonatephenyl)porphyrinatezinc(II), forming alternating layers onto glassy carbon surfaces. The films were studied by cyclic voltammetry and proved to be strongly adherent and highly stable. They could be used for at least a week without loss of sensitivity. In addition, they exhibit an enhanced amperometric response and good protection against fouling, e.g., by phenol oxidation products. Their usefulness in flow injection analysis of NO2- and SO32- was demonstrated. Excellent signal to noise ratios were obtained for SO32- down to 10^-6 mol/L, and for NO2- down to 10^-7 mol/L.',
'language' => 'English',
'updated' => '2020-12-28 11:25:15',
'sjccheck' => 'Yes',
'sjccheckdate' => '0000-00-00 00:00:00',
'hits' => '17',
'urlcheck' => '2014-10-11 14:12:28',
'urlcheckcode' => 'HTTP/1.1 302 Found',
'pauthor_id' => '01348',
'pauthor' => '!Toma, H.E.',
'address' => 'pau',
'email' => 'pau',
'notes' => null,
'url' => '10.1002/(SICI)1521-4109(199806)10:7<467::AID-ELAN467>3.0.CO;2-W',
'urltype' => 'doi',
'gotpdf' => 'yes',
'partial' => 'no',
'notanalyte' => '',
'citation' => ''Electrostatically assembled films for improving the properties of tetraruthenated porphyrin-modified electrodes', Electroanalysis, 1998 10(7) 467-471',
'firstchar' => 'E',
'twochars' => 'El',
'CitationsTechnique' => array(
[maximum depth reached]
),
'Analyte' => array(
[maximum depth reached]
),
'Matrix' => array([maximum depth reached]),
'Keyword' => array(
[maximum depth reached]
)
)
)
)
$c = array(
'id' => '009970',
'authors' => 'Azevedo, C.M.N.;Araki, K.;Angnes, L.;Toma, H.E.',
'authorsweb' => 'Carla M.N. Azevedo, Koiti Araki, Lúcio Angnes, Henrique E. Toma',
'title' => 'Electrostatically assembled films for improving the properties of tetraruthenated porphyrin-modified electrodes',
'journal' => 'Electroanalysis',
'journal_id' => '1003',
'fadid' => 'ELAN1998V0010P00467',
'year' => '1998',
'volume' => '10',
'issue' => '7',
'startpage' => '467',
'endpage' => '471',
'type' => 'Journal Article',
'analytes' => ';2242;1592;',
'matrices' => '',
'techniques' => ';0001;0093;0127;',
'keywords' => ';0043;0110;',
'abstract' => 'Modified electrodes, suitable for use in flow injection anal., were obtained by the electrostatic assembly of films constituted by 2 different porphyrins, namely, µ-meso(tetrapyridyl)porphyrinatecobalt(III)tetrakis[bis(bipyridine)(chloro)ruthenium(II)] and meso-tetra(4-sulfonatephenyl)porphyrinatezinc(II), forming alternating layers onto glassy carbon surfaces. The films were studied by cyclic voltammetry and proved to be strongly adherent and highly stable. They could be used for at least a week without loss of sensitivity. In addition, they exhibit an enhanced amperometric response and good protection against fouling, e.g., by phenol oxidation products. Their usefulness in flow injection analysis of NO2- and SO32- was demonstrated. Excellent signal to noise ratios were obtained for SO32- down to 10^-6 mol/L, and for NO2- down to 10^-7 mol/L.',
'language' => 'English',
'updated' => '2020-12-28 11:25:15',
'sjccheck' => 'Yes',
'sjccheckdate' => '0000-00-00 00:00:00',
'hits' => '17',
'urlcheck' => '2014-10-11 14:12:28',
'urlcheckcode' => 'HTTP/1.1 302 Found',
'pauthor_id' => '01348',
'pauthor' => '!Toma, H.E.',
'address' => 'pau',
'email' => 'pau',
'notes' => null,
'url' => '10.1002/(SICI)1521-4109(199806)10:7<467::AID-ELAN467>3.0.CO;2-W',
'urltype' => 'doi',
'gotpdf' => 'yes',
'partial' => 'no',
'notanalyte' => '',
'citation' => ''Electrostatically assembled films for improving the properties of tetraruthenated porphyrin-modified electrodes', Electroanalysis, 1998 10(7) 467-471',
'firstchar' => 'E',
'twochars' => 'El',
'CitationsTechnique' => array(
'id' => '008737',
'citation_id' => '009970',
'technique_id' => '0093'
),
'Analyte' => array(
(int) 0 => array(
'id' => '02242',
'name' => 'Sulfite',
'iupac_name' => 'sulfite',
'casrn' => '14265-45-3',
'synonyms' => 'Sulfite; Sulfite anion; Sulfites',
'total' => '76',
'inchi' => 'InChI=1S/H2O3S/c1-4(2)3/h(H2,1,2,3)/p-2',
'inchikey' => 'LSNNMFCWUKXFEE-UHFFFAOYSA-L',
'formula' => 'O3S-2',
'oxstate' => '+4',
'url' => '',
'charge' => '-2',
'class1' => 'Inorganic compound',
'class2' => 'NA',
'class3' => 'NA',
'class4' => 'Anion',
'class5' => 'Acids',
'isgroup' => '',
'checked' => 'yes',
'citation_count' => '0',
'updated' => '2015-10-23 21:37:42',
'first' => 'S',
'nametotal' => 'Sulfite**76',
'AnalytesCitation' => array(
[maximum depth reached]
)
),
(int) 1 => array(
'id' => '01592',
'name' => 'Nitrite',
'iupac_name' => 'nitrite',
'casrn' => '14797-65-0',
'synonyms' => 'Nitrite; Nitrite ; Nitrites; Nitrites, inorganic, aqueous solution, n.o.s.; Nitrites, inorganic, n.o.s.; Nitrite ion',
'total' => '174',
'inchi' => 'InChI=1S/HNO2/c2-1-3/h(H,2,3)/p-1',
'inchikey' => 'IOVCWXUNBOPUCH-UHFFFAOYSA-M',
'formula' => 'NO2-',
'oxstate' => '+3',
'url' => '',
'charge' => '-1',
'class1' => 'Inorganic compound',
'class2' => 'NA',
'class3' => 'NA',
'class4' => 'Anion',
'class5' => '',
'isgroup' => '',
'checked' => 'yes',
'citation_count' => '0',
'updated' => '2015-10-23 21:32:42',
'first' => 'N',
'nametotal' => 'Nitrite**174',
'AnalytesCitation' => array(
[maximum depth reached]
)
)
),
'Matrix' => array(),
'Keyword' => array(
(int) 0 => array(
'id' => '0043',
'type' => 'Manifold component',
'keyword' => 'Apparatus',
'newKeyword' => '',
'synonyms' => '',
'fao' => '',
'total' => '466',
'first' => 'A',
'keytotal' => 'Apparatus**466',
'CitationsKeyword' => array(
[maximum depth reached]
)
),
(int) 1 => array(
'id' => '0110',
'type' => 'Manifold component',
'keyword' => 'Detector',
'newKeyword' => '',
'synonyms' => '',
'fao' => '',
'total' => '354',
'first' => 'D',
'keytotal' => 'Detector**354',
'CitationsKeyword' => array(
[maximum depth reached]
)
)
)
)
$i = (int) 0
$path = ''
$a = ''
$url = 'http://dx.doi.org/10.1002/(SICI)1521-4109(199806)10:7<467::AID-ELAN467>3.0.CO;2-W'
$aus = 'Carla M.N. Azevedo, Koiti Araki, L&uacute;cio Angnes, Henrique E. Toma'
include - APP/View/Elements/citation.ctp, line 40
View::_evaluate() - CORE/Cake/View/View.php, line 971
View::_render() - CORE/Cake/View/View.php, line 933
View::_renderElement() - CORE/Cake/View/View.php, line 1224
View::element() - CORE/Cake/View/View.php, line 418
include - APP/View/Techniques/view.ctp, line 52
View::_evaluate() - CORE/Cake/View/View.php, line 971
View::_render() - CORE/Cake/View/View.php, line 933
View::render() - CORE/Cake/View/View.php, line 473
Controller::render() - CORE/Cake/Controller/Controller.php, line 968
Dispatcher::_invoke() - CORE/Cake/Routing/Dispatcher.php, line 200
Dispatcher::dispatch() - CORE/Cake/Routing/Dispatcher.php, line 167
[main] - APP/webroot/index.php, line 109
Carla M.N. Azevedo, Koiti Araki, Lúcio Angnes, Henrique E. Toma
Abstract:
Modified electrodes, suitable for use in flow injection anal., were obtained by the electrostatic assembly of films constituted by 2 different porphyrins, namely, µ-meso(tetrapyridyl)porphyrinatecobalt(III)tetrakis[bis(bipyridine)(chloro)ruthenium(II)] and meso-tetra(4-sulfonatephenyl)porphyrinatezinc(II), forming alternating layers onto glassy carbon surfaces. The films were studied by cyclic voltammetry and proved to be strongly adherent and highly stable. They could be used for at least a week without loss of sensitivity. In addition, they exhibit an enhanced amperometric response and good protection against fouling, e.g., by phenol oxidation products. Their usefulness in flow injection analysis of NO2- and SO32- was demonstrated. Excellent signal to noise ratios were obtained for SO32- down to 10^-6 mol/L, and for NO2- down to 10^-7 mol/L.
Sulfite
Nitrite
Apparatus
Detector
