FAD: Techniques

Contact Info

Stuart Chalk, Ph.D.
Department of Chemistry
University of North Florida
Phone: 1-904-620-1938
Fax: 1-904-620-3535
Email: schalk@unf.edu
Website: @unf

Electrode

Classification: Electrode -> bubble

Citations 4

'Properties Of The Bubble-electrode, A New Electrochemical Flow-through Detector', Fresenius J. Anal. Chem., 1984 318(5) 352-353

"Properties Of The Bubble-electrode, A New Electrochemical Flow-through Detector"
Fresenius J. Anal. Chem. 1984 Volume 318, Issue 5 Pages 352-353

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Fritz Scholz and Günter Henrion

Abstract: UFL

Apparatus Detector

'Tensammetry With The Bubble-electrode In A Flow-through System', Fresenius J. Anal. Chem., 1987 326(8) 774-776

"Tensammetry With The Bubble-electrode In A Flow-through System"
Fresenius J. Anal. Chem. 1987 Volume 326, Issue 8 Pages 774-776

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Fritz Scholz, Michael Kupfer, Jürgen Seelisch, Gerd Glowacz and Günter Henrion

Abstract: The construction of a bubble-electrode is described, which was used for tensammetry in a flow-through system. The properties of the electrode response were studied with ac-voltammetry and phase sensitive ac-voltammetry (fundamental and second harmonic mode) using ethyleneoxide-propyleneoxide polymers.

'Bubbleelectrodes - New Flow-through Electrodes For Analytical, Preparative And Spectroscopical Applications', Z. Chem., 1985 25(4) 121-125

"Bubbleelectrodes - New Flow-through Electrodes For Analytical, Preparative And Spectroscopical Applications"
Z. Chem. 1985 Volume 25, Issue 4 Pages 121-125

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Fritz Scholz, Günter Henrion

Abstract: A review is presented, with 22 references, in which the theory and applications of bubble electrodes are discussed. Such electrodes find applications in electrolysis, e.s.r., and detection in HPLC or flow injection analysis.

Cadmium Review

'Spectrophotometric Flow-through Method For The Determination Of Phosphate After Reduction Of Molybdophosphoric Acid At A Bubble Electrode', Z. Chem., 1986 26(8) 298-299

"Spectrophotometric Flow-through Method For The Determination Of Phosphate After Reduction Of Molybdophosphoric Acid At A Bubble Electrode"
Z. Chem. 1986 Volume 26, Issue 8 Pages 298-299

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Fritz Scholz, Günter Henrion, Kerstin Weinberg

Abstract: Molybdophosphoric acid is reduced to phosphomolybdenum blue by passage through a cell with mercury and mercury - HgCl2 electrodes, of low dead volume and containing an ion-exchange membrane, which is coupled to a continuous-flow colorimeter. With reduction at -0.3 V vs. silver - AgCl, the calibration graph is rectilinear in the range 10 µM to 0.5 mM PO43-. The coefficient of variation (n = 10) is 1.9% at 0.4 mM.

Phosphate Electrochemical product conversion