Contact Info
Stuart Chalk, Ph.D.
Department of Chemistry
University of North Florida
Phone: 1-904-620-1938
Fax: 1-904-620-3535
Email: schalk@unf.edu
Website: @unf
Amperometry
Citations 2
"Reductive Amperometric Determination Of Nitrofurantoin And Acetazolamide At A Sessile Mercury Drop Electrode Using Flow Injection Analysis"
Analyst
1988 Volume 113, Issue 5 Pages 727-730
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"Assessment Of Online Nitration Reactions As A Means Of Determining Nitrate By Reverse Flow Injection With Reductive Amperometric Detection At A Glassy Carbon Electrode"
Analyst
1989 Volume 114, Issue 5 Pages 579-581
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Problems associated with contamination of the electrode surface with reduction product, which caused loss of signal after making repeated injections over an extended period, remained.', 'language' => 'English', 'updated' => '2020-12-28 11:25:15', 'sjccheck' => 'Yes', 'sjccheckdate' => '0000-00-00 00:00:00', 'hits' => '7', 'urlcheck' => '2014-10-12 00:04:12', 'urlcheckcode' => 'HTTP/1.1 302 Found', 'pauthor_id' => null, 'pauthor' => 'NA', 'address' => 'NA', 'email' => 'NA', 'notes' => null, 'url' => '10.1039/an9891400579', 'urltype' => 'doi', 'gotpdf' => 'yes', 'partial' => 'no', 'notanalyte' => '', 'citation' => ''Assessment of online nitration reactions as a means of determining nitrate by reverse flow injection with reductive amperometric detection at a glassy carbon electrode', Analyst, 1989 114(5) 579-581', 'firstchar' => 'A', 'twochars' => 'As', 'CitationsTechnique' => array( [maximum depth reached] ), 'Analyte' => array( [maximum depth reached] ), 'Matrix' => array([maximum depth reached]), 'Keyword' => array( [maximum depth reached] ) ) ) ) $c = array( 'id' => '007553', 'authors' => 'Fogg, A.G.;Scullion, S.P.;Edmonds, T.E.', 'authorsweb' => 'Arnold G. Fogg, S. Paul Scullion and Tony E. Edmonds', 'title' => 'Assessment of online nitration reactions as a means of determining nitrate by reverse flow injection with reductive amperometric detection at a glassy carbon electrode', 'journal' => 'Analyst', 'journal_id' => '0864', 'fadid' => 'ANAL1989V0114P00579', 'year' => '1989', 'volume' => '114', 'issue' => '5', 'startpage' => '579', 'endpage' => '581', 'type' => 'Journal Article', 'analytes' => ';1588;', 'matrices' => '', 'techniques' => ';0010;0226;', 'keywords' => ';0387;', 'abstract' => 'Five compounds were investigated for use as on-line reagents in concentrated sulphuric acid for the reductive reverse flow injection amperometric determination of nitrate as a nitro derivative at a glassy carbon electrode. The sulphuric acid was diluted rapidly on injecting the reagent solution into a sample carrier stream and therefore the nitration reaction, which generally only takes place at sulphuric acid concentrations of greater than about 70%, had to be rapid. Thiophene-2-carboxylic acid was found to be the most suitable reagent of those studied. The nitration reaction was sufficiently rapid and the first of two reduction steps was at -0.19 V versus SCE (as indicated by linear sweep voltammetry); hence the determination was free from interference by dissolved oxygen. 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