"Anodic Amperometry And Kinetics Of 2 To 4-carbon Glycols At The Nickel Electrode"
Anal. Chim. Acta 1988 Volume 208, Issue 1-2 Pages 247-254

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"Improved Mediated Tyrosinase Amperometric Enzyme Electrodes"
J. Electroanal. Chem. 1997 Volume 425, Issue 1-2 Pages 1-11

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		'title' => 'Improved mediated tyrosinase amperometric enzyme electrodes',
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		'abstract' => 'The electroreduction of the quinonoid products of the oxidation of phenols by monophenol monooxygenase in carbon-paste electrodes to two-electron-donating phenolic species in order to regenerate the active (oxy-) form of the enzyme in the presence of O2 has been made more efficient by the incorporation of bis-(4,4'-dimethyl-2,2'-bipyridyl)(1,10-phenanthroline-5,6-dione)osmium chloride as mediator in the carbon paste. The reduction-current response was thereby rendered mass-transport-limited. Both batch cyclic-voltammetric and flow injection experiments are described. Under flow injection conditions the presence of the mediator increased the current density threefold, decreased the detection limit by nearly two orders of magnitude, and increased the lifetime by more than one order of magnitude. For injection of a 20 &micro;L sample into a carrier stream of 0.25 M phosphate buffer of pH 6.0 (0.7 ml/min) with the electrode maintained at -0.5 V vs. Ag/AgCl, the detection limits for phenol and catechol were both 10 nM, as compared with 500 nM and 250 nM, respectively, in the absence of the mediator.',
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"Flow Injection Analysis With Amperometric Detection Of Naltrexone In Pharmaceuticals"
J. Pharm. Biomed. Anal. 1997 Volume 16, Issue 1 Pages 15-19

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			'abstract' => 'The electroreduction of the quinonoid products of the oxidation of phenols by monophenol monooxygenase in carbon-paste electrodes to two-electron-donating phenolic species in order to regenerate the active (oxy-) form of the enzyme in the presence of O2 has been made more efficient by the incorporation of bis-(4,4'-dimethyl-2,2'-bipyridyl)(1,10-phenanthroline-5,6-dione)osmium chloride as mediator in the carbon paste. The reduction-current response was thereby rendered mass-transport-limited. Both batch cyclic-voltammetric and flow injection experiments are described. Under flow injection conditions the presence of the mediator increased the current density threefold, decreased the detection limit by nearly two orders of magnitude, and increased the lifetime by more than one order of magnitude. For injection of a 20 &micro;L sample into a carrier stream of 0.25 M phosphate buffer of pH 6.0 (0.7 ml/min) with the electrode maintained at -0.5 V vs. Ag/AgCl, the detection limits for phenol and catechol were both 10 nM, as compared with 500 nM and 250 nM, respectively, in the absence of the mediator.',
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			'url' => '10.1016/S0022-0728(96)04966-2',
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			'citation' => ''Improved mediated tyrosinase amperometric enzyme electrodes', J. Electroanal. Chem., 1997 425(1-2) 1-11',
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			'title' => 'Flow injection analysis with amperometric detection of naltrexone in pharmaceuticals',
			'journal' => 'J. Pharm. Biomed. Anal.',
			'journal_id' => '0632',
			'fadid' => 'JPBA1997V0016P00015',
			'year' => '1997',
			'volume' => '16',
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			'abstract' => 'Flow injection analysis (FIA) with amperometric detection using a carbon paste electrode is applied to the determination of naltrexone. The sample solution was injected into the carrier stream of 0.1 M perchloric acid, being determined by oxidation at +1.0 V vs. Ag/AgCl/sat. KCl using a flow rate of 4 mL min-1. A relative standard deviation of 1.5% was calculated for a concentration level of 10^-5 M (n = 17) without carrying out a carbon paste electrode pretreatment. Calibration curves were found to be linear between 2 x 10^-8 and 10^-5 M (almost three orders of magnitude) and the method has a detection limit of 2 x 10^-8 M. A simple and reproducible procedure is proposed for the determination of naltrexone in pharmaceuticals. The results compared favourably with those obtained by an HPLC-UV method.',
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			'notes' => null,
			'url' => '10.1016/S0731-7085(96)01962-0',
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	'title' => 'Flow injection analysis with amperometric detection of naltrexone in pharmaceuticals',
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include - APP/View/Elements/citation.ctp, line 40
View::_evaluate() - CORE/Cake/View/View.php, line 971
View::_render() - CORE/Cake/View/View.php, line 933
View::_renderElement() - CORE/Cake/View/View.php, line 1224
View::element() - CORE/Cake/View/View.php, line 418
include - APP/View/Techniques/view.ctp, line 52
View::_evaluate() - CORE/Cake/View/View.php, line 971
View::_render() - CORE/Cake/View/View.php, line 933
View::render() - CORE/Cake/View/View.php, line 473
Controller::render() - CORE/Cake/Controller/Controller.php, line 968
Dispatcher::_invoke() - CORE/Cake/Routing/Dispatcher.php, line 200
Dispatcher::dispatch() - CORE/Cake/Routing/Dispatcher.php, line 167
[main] - APP/webroot/index.php, line 109