University of North Florida
Browse the Citations

Contact Info

Stuart Chalk, Ph.D.
Department of Chemistry
University of North Florida
Phone: 1-904-620-1938
Fax: 1-904-620-3535
Website: @unf

View Stuart Chalk's profile on LinkedIn

Inorganic compound

Classification: Inorganic compound -> perchloric acid

Citations 1

"Catalytic Determination Of Manganese At Ultratrace Levels By Flow Injection Analysis"
Analyst 1986 Volume 111, Issue 1 Pages 69-72
S. Maspoch, M. Blanco and V. Cerdá

Abstract: The catalytic effect of Mn(II) on the oxidation of succinimide dioxime in alkaline medium was used for determination of Mn(II) by flow injection analysis with photometric detection at 695 nm. Variation of the reaction temperature between 25°C and 45°C allows the determination range to be extended from 0.2 to 1300 ng mL-1, with a sampling frequency of 45 h-1 and a coefficient of variation of 1.3 to 1.0%. Injection of the sample in a flow of EDTA solution overcomes most interference. Interference by Co(II), Fe(II) and Mg(II) was investigated. The method was used to determine Mn in reagent-grade ZnO and HClO4 and in powdered coffee and rice.
Manganese(II) Spectrophotometry Catalysis Heated reaction Interferences Optimization Ultratrace