University of North Florida
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Stuart Chalk, Ph.D.
Department of Chemistry
University of North Florida
Phone: 1-904-620-1938
Fax: 1-904-620-3535
Email: schalk@unf.edu
Website: @unf

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Copper concentrates

Citations 1

"Elimination Of Interferences From Copper, Lead, Silver, Gold, Platinum, Palladium And Selenium In The Determination Of Mercury By CVAAS Using Sodium Tetrahydroborate(III) Reduction In Copper Concentrates"
Fresenius J. Anal. Chem. 1994 Volume 350, Issue 3 Pages 178-180
Ewa Szmyd and Irena Baranowska

Abstract: The determination of mercury in the presence of Cu, Pb, Ag, Au, Pt, Pd, Se and As by cold vapor atomic absorption spectrometry was studied. Sodium tetrahydroborate(III) was used as a reducing agent. All the elements examined except arsenic exhibited strong interferences. A solution of 1,10-phenanthroline and thiosemicarbazide in 1.5% HCl solution was used as a masking agent. A highly effective reduction of interference by Cu, Ag, Au, Pt, Pd and Se was achieved. The results obtained were applied to the determination of mercury in a copper concentrate.
Mercury Spectrophotometry Interferences Volatile generation Volatile generation