Contact Info
Stuart Chalk, Ph.D.
Department of Chemistry
University of North Florida
Phone: 1-904-620-1938
Fax: 1-904-620-3535
Email: schalk@unf.edu
Website: @unf
Glass Technology
- Publisher:
- FAD Code: GLTC
- CODEN: GLSTAK
- ISSN: 0017-1050
- Abbreviation: Glass Technol.
- DOI Prefix: NA
- Other Name(s): Glass Technology - European Journal of Glass Science and Technology Part A
- Language: English
- Comments: Fulltext from 1998 V39
Citations 1
"A Collaborative Study For The Determination Of Mercury In Glass Packaging By Cold Vapor Atomic Absorption Spectrometry - A Report Of ICG/TC2, Chemical Durability And Analysis"
Glass Technol.
2001 Volume 42, Issue 1 Pages 24-29
E.Guadagnino, P.Sundberg and H.J.Heinrich
Abstract:
Within the frame of the requirements set out by the Packaging Directive 62/94, this paper recommends a method for the determination of mercury by cold vapor atomic absorption spectrometry (CVAAS). The study consisted of two ports: (i) a recovery study.; (ii) a collaborative intercomparison carried out on an experimental glass incorporating Hg in traces. During the recovery study the decomposition solution of a Hg free container glass was spiked with known amounts of Hg which were fully recovered by CVAAS. No significant interferences were found from other hydride forming elements. An intercomparison among ten laboratories carried out on a glass incorporating Hg traces showed an acceptable reproducibility (CV 8.9%) at a mean concentration level of 1.10 mg/kg. The determination limit was estimated as 0.1 mg Hg/kg of glass. Inductively coupled plasma optical emission spectrometry (ICP-OES), used as an alternative to CVAAS, showed a limit of determination of 7.2 mg/kg, which was considered quite inadequate, with respect to the average mean value of Hg possibly present in packaging.
Mercury
Commercial product
Spectrophotometry
Interferences
Method comparison