Contact Info
Stuart Chalk, Ph.D.
Department of Chemistry
University of North Florida
Phone: 1-904-620-1938
Fax: 1-904-620-3535
Email: schalk@unf.edu
Website: @unf
1-[(1-hydroperoxycyclohexyl)peroxy]cyclohexanol
- IUPAC Name: 1-(1-hydroperoxycyclohexyl)peroxycyclohexan-1-ol
- Molecular Formula: C12H22O5
- CAS Registry Number: 78-18-2
- InChI: InChI=1S/C12H22O5/c13-11(7-3-1-4-8-11)16-17-12(15-14)9-5-2-6-10-12/h13-14H,1-10H2
- InChI Key: UICXTANXZJJIBC-UHFFFAOYSA-N
Citations 1
"Liquid Chromatography And Electrochemical Detection Of Organic Peroxides By Reduction At An Iron Phthalocyanine Chemically Modified Electrode"
Electroanalysis
1993 Volume 5, Issue 7 Pages 547-554
Xiaohe Qi, Richard P. Baldwin
Abstract:
Iron phthalocyanine (2%) was incorporated into carbon paste to form an electrode that could be used in 0.05 M phosphate buffer at pH 2 for the amperometric detection of organic peroxides (excluding dialkyl peroxides) at +0.1 V (minimum) vs. Ag/AgCl. Detection limits (pmol) measured for operation at +0.35 V ranged from 0.13 for peracetic acid to 300 for 1-[(1-hydroperoxycyclohexyl)dioxy]cyclohexanol. No response was shown for a 500-pmol injection of t-butyl peroxide, but the detection limit was 1.0 pmol for 2-butanone peroxide. The method was suitable for use in FIA or HPLC and 10% acetonitrile could be added to the mobile phase.
Electrode
Electrode